南方科技大学知识苑(SUSTech KC): Thermodynamic performance analysis of the influence of multi-factor coupling on the methanol steam reforming reaction

题名	Thermodynamic performance analysis of the influence of multi-factor coupling on the methanol steam reforming reaction
作者	Xing, Shuang1 ; Zhao, Chen1 ; Ban, Shuai 2; Liu, Yifan1 ; Wang, Haijiang1
通讯作者	Zhao, Chen
发表日期	2020
DOI	10.1016/j.ijhydene.2019.12.192
发表期刊	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 影响因子和分区
ISSN	0360-3199
EISSN	1879-3487
卷号	45 期号:11页码:7015-7024
摘要	This work presents the H2 production from methanol steam reforming (MSR) process by thermodynamic equilibrium analysis using the Gibbs free energy minimization method and multi-factor coupling method. To determine desirable procedure parameters with maximum methanol conversion and H2 content and minimum CO content, the impacts of the temperature: 100–400 °C, steam-to-methanol (S/C) molar ratio: 1.0–3.0, and pressure: 0.5–3.0 atm were investigated. The dominant factor under the action of multiple factors and the specific influence of each factor on the MSR process were verified, simultaneously. For proton exchange membrane fuel cell (PEMFC), to keep the CO content of the reformate within a desired range, and under the premise of complete methanol conversion, the MSR process can be operated at lower temperature, higher S/C ratio and atmospheric pressure. Combined with practice process, the optimum values of the temperature, S/C ratio and pressure to produce reformate were identified to be 200–300 °C,1.6–2.0 and 1.0 atm, respectively. © 2020 Hydrogen Energy Publications LLC
关键词	Methanol steam reforming Hydrogen Fuel cell Thermodynamics Simulation
相关链接	[来源记录]
收录类别	EI ; SCI
语种	英语
学校署名	第一 ; 通讯
资助项目	National Basic Research Program of China (973 Program)[2017YFB0102701] ; Development and Reform Commission of Shenzhen Municipality[1106] ; Shenzhen Peacock Plan[KQTD2016022620054656] ; [2018B030322001] ; Guangdong Innovative and Entrepreneurial Research Team Program[2016ZT06N500]
WOS研究方向	Chemistry ; Electrochemistry ; Energy & Fuels
WOS类目	Chemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS记录号	WOS:000519652800088
出版者	Elsevier Ltd
EI入藏号	20200508118683
EI主题词	Atmospheric pressure ; Atmospheric temperature ; Factor analysis ; Free energy ; Fuel cells ; Gibbs free energy ; Hydrogen ; Hydrogen production ; Methanol ; Molar ratio ; Proton exchange membrane fuel cells (PEMFC) ; Steam ; Thermodynamics
EI分类号	Atmospheric Properties:443.1 ; Gas Fuels:522 ; Thermodynamics:641.1 ; Fuel Cells:702.2 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Organic Compounds:804.1 ; Mathematical Statistics:922.2
ESI学科分类	ENGINEERING
来源库	EV Compendex
引用统计	被引频次[WOS]：29
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/104465
专题	南方科技大学工学院_机械与能源工程系
作者单位	1.Southern University of Science and Technology, Shenzhen; 518055, China 2.China University of Petroleum, Beijing, Beijing; 102200, China
第一作者单位	南方科技大学
通讯作者单位	南方科技大学
第一作者的第一单位	南方科技大学
推荐引用方式 GB/T 7714	Xing, Shuang,Zhao, Chen,Ban, Shuai,et al. Thermodynamic performance analysis of the influence of multi-factor coupling on the methanol steam reforming reaction[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2020,45(11):7015-7024.
APA	Xing, Shuang,Zhao, Chen,Ban, Shuai,Liu, Yifan,&Wang, Haijiang.(2020).Thermodynamic performance analysis of the influence of multi-factor coupling on the methanol steam reforming reaction.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,45(11),7015-7024.
MLA	Xing, Shuang,et al."Thermodynamic performance analysis of the influence of multi-factor coupling on the methanol steam reforming reaction".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 45.11(2020):7015-7024.