An Update on Formic Acid Dehydrogenation by Homogeneous Catalysis

Guan, Chao1,2; Pan, Yupeng1,2,3; Zhang, Tonghuan1,2,4; Ajitha, Manjaly J.1,2; Huang, Kuo-Wei1,2

2020-02-25

10.1002/asia.201901676

Chemistry-An Asian Journal   影响因子和分区

1861-4728

1861-471X

Formic acid (FA) has been extensively studied as one of the most promising hydrogen energy carriers today. The catalytic decarboxylation of FA ideally leads to the formation of CO2 and H-2 that can be applied in fuel cells. A large number of transition-metal based homogeneous catalysts with high activity and selectivity have been reported for the selective FA dehydrogentaion. In this review, we discussed the recent development of C,N/N,N-ligand and pincer ligand-based homogeneous catalysts for the FA dehydrogenation reaction. Some representative catalysts are further evaluated by the CON/COF assessment (catalyst on-cost number)/(catalyst on-cost frequency). Conclusive remarks are provided with future challenges and opportunities.

formic acid hydrogen energy carrier homogeneous catalysis

SCI ; EI

英语

其他

Chemistry

Chemistry, Multidisciplinary

WOS:000515405900001

WILEY-V C H VERLAG GMBH

20200908243326

Dehydrogenation ; Ligands ; Transition metals ; Catalyst activity ; Catalyst selectivity ; Catalysis ; Carboxylation ; Fuel cells

Metallurgy and Metallography:531 ; Fuel Cells:702.2 ; Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1

Web of Science

1.King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr, Thuwal 239556900, Saudi Arabia
2.King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia
3.Southern Univ Sci & Technol SUSTech, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China
4.Peking Univ, Shenzhen Grad Sch, Lab Computat Chem & Drug Design, State Key Lab Chem Oncogen, Shenzhen 518055, Peoples R China

Guan, Chao,Pan, Yupeng,Zhang, Tonghuan,et al. An Update on Formic Acid Dehydrogenation by Homogeneous Catalysis[J]. Chemistry-An Asian Journal,2020,15(7):937-946.

Guan, Chao,Pan, Yupeng,Zhang, Tonghuan,Ajitha, Manjaly J.,&Huang, Kuo-Wei.(2020).An Update on Formic Acid Dehydrogenation by Homogeneous Catalysis.Chemistry-An Asian Journal,15(7),937-946.

Guan, Chao,et al."An Update on Formic Acid Dehydrogenation by Homogeneous Catalysis".Chemistry-An Asian Journal 15.7(2020):937-946.