| 题名 | A Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Alkynes to (E)-Alkenes with Ethanol |
| 作者 | |
| 通讯作者 | Yang，Weiwei; Xia，Haiping; Chen，Dafa |
| 发表日期 | 2020
|
| DOI | |
| 发表期刊 | |
| ISSN | 0276-7333
|
| EISSN | 1520-6041
|
| 卷号 | 39期号:6页码:862-869 |
| 摘要 | Four Ru(II)-NC complexes were tested as catalysts for semihydrogenation of internal alkynes to (E)-alkenes with ethanol, and the complex {(CHN)(CH)}RuCl(CO)(PPh) (1a) showed the highest activity. The reactions proceeded well with 1 mol % catalyst loading and 0.1 equiv of t-BuONa at 110 °C for 1 h, and 32 alkenes were synthesized with excellent E:Z selectivity. This is the first ruthenium-catalyzed semihydrogenation of internal alkynes to (E)-alkenes using ethanol as the hydrogen donor. |
| 相关链接 | [Scopus记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 通讯
|
| 资助项目 | National Natural Science Foundation of Heilongjiang[B2018005]
; National Natural Science Foundation of Heilongjiang[LC2018005]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Inorganic & Nuclear
; Chemistry, Organic
|
| WOS记录号 | WOS:000526340300014
|
| 出版者 | |
| EI入藏号 | 20201108303552
|
| EI主题词 | Ethanol
; Synthesis (chemical)
; Ruthenium compounds
; Catalyst selectivity
|
| EI分类号 | Chemical Reactions:802.2
; Chemical Agents and Basic Industrial Chemicals:803
; Chemical Products Generally:804
; Organic Compounds:804.1
|
| ESI学科分类 | CHEMISTRY
|
| Scopus记录号 | 2-s2.0-85081677669
|
| 来源库 | Scopus
|
| 引用统计 |
被引频次[WOS]：23
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/106428 |
| 专题 | 理学院_化学系 深圳格拉布斯研究院 |
| 作者单位 | 1.Miit Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage,School of Chemical Engineering and Technology,Harbin Institute of Technology,Harbin,150001,China 2.Shenzhen Grubbs Institute,Department of Chemistry,Southern University of Science and Technology,Shenzhen,China |
| 第一作者单位 | 化学系; 深圳格拉布斯研究院 |
| 通讯作者单位 | 化学系; 深圳格拉布斯研究院 |
| 推荐引用方式 GB/T 7714 |
Gong，Dawei,Hu，Bowen,Yang，Weiwei,et al. A Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Alkynes to (E)-Alkenes with Ethanol[J]. ORGANOMETALLICS,2020,39(6):862-869.
|
| APA |
Gong，Dawei,Hu，Bowen,Yang，Weiwei,Kong，Degong,Xia，Haiping,&Chen，Dafa.(2020).A Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Alkynes to (E)-Alkenes with Ethanol.ORGANOMETALLICS,39(6),862-869.
|
| MLA |
Gong，Dawei,et al."A Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Alkynes to (E)-Alkenes with Ethanol".ORGANOMETALLICS 39.6(2020):862-869.
|
| 条目包含的文件 | 条目无相关文件。 | |||||
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