Reticular chemistry in electrochemical carbon dioxide reduction

Wang, Yanfang1,2,4; Li, Yuexiang3; Wang, Zhenyu1; Allan, Phoebe4; Zhang, Fucai2; Lu, Zhouguang1

2020-04-28

10.1007/s40843-020-1304-3

Science China-Materials   影响因子和分区

2095-8226

2199-4501

Electrochemical CO2 reduction (ECR) represents a promising strategy for utilizing CO2, an industrial waste, as an abundant and cheap carbon source for organic synthesis as well as storing intermittent renewable electricity from renewable sources. Efficient electrocatalysts allowing CO2 to be reduced selectively and actively are crucial since the ECR is a complex and sluggish process producing a variety of products. Metal-organic frameworks (MOFs) and covalentorganic frameworks (COFs) have emerged as versatile materials applicable in many fields due to their unique properties including high surface areas and tunable pore channels. Besides, the emerging reticular chemistry makes tuning their features on the atomic/molecular levels possible, thereby lending credence to the prospect of their utilizations. Herein, an overview of recent progress in employing framework material-based catalysts, including MOFs, COFs and their derivatives, for ECR is provided. The pertinent challenges, future trends, and opportunities associated with those systems are also discussed.

reticular chemistry MOFs COFs electrochemistry carbon dioxide reduction

SCI ; EI

英语

第一 ; 通讯

National Natural Science Foundation of China[21671096][11775105] ; Shenzhen Peacock Plan[KQTD2016022620054656]

Materials Science

Materials Science, Multidisciplinary

WOS:000529583100001

SCIENCE PRESS

20202108690499

Electrocatalysts ; Metal-Organic Frameworks ; Pollution control ; Organic carbon

Metallurgy:531.1 ; Chemical Agents and Basic Industrial Chemicals:803 ; Organic Compounds:804.1 ; Inorganic Compounds:804.2

Web of Science

1.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
2.Southern Univ Sci & Technol, Dept Elect & Elect Engn, Shenzhen 518055, Peoples R China
3.Alibaba Shenzhen Technol Co Ltd, Alibaba Cloud, Shenzhen 518000, Peoples R China
4.Univ Birmingham, Sch Chem, Birmingham B15 2NT, W Midlands, England

Wang, Yanfang,Li, Yuexiang,Wang, Zhenyu,et al. Reticular chemistry in electrochemical carbon dioxide reduction[J]. Science China-Materials,2020,63(7):1113-1141.

Wang, Yanfang,Li, Yuexiang,Wang, Zhenyu,Allan, Phoebe,Zhang, Fucai,&Lu, Zhouguang.(2020).Reticular chemistry in electrochemical carbon dioxide reduction.Science China-Materials,63(7),1113-1141.

Wang, Yanfang,et al."Reticular chemistry in electrochemical carbon dioxide reduction".Science China-Materials 63.7(2020):1113-1141.