Organoboron-Functionalization Enables the Hierarchical Assembly of Giant Polyoxometalate Nanocapsules

Li, Shujun1; Zhou, Yanfang1; Ma, Nana1; Zhang, Jie1; Zheng, Zhiping2,3; Streb, Carsten4; Chen, Xuenian1,5

2020-05-25

10.1002/anie.202003550

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   影响因子和分区

1433-7851

1521-3773

Giant nanocapsules with dimensions of up to 4 nm and a molecular weight of 57 kDa were obtained from Dawson-type polyoxometalates functionalized with aromatic boronic acids, as reported by Z. Zheng, C. Streb, X. Chen, et al. in their Communication (DOI: 10.1002/anie.202003550). A "lock-and-key" organofunctionalization route was used for the regiospecific attachment of the boronic acids to pre-functionalized sites within the Dawson anions. This results in the aggregation of closed capsules rather than infinite networks.

boronic acid organo-functionalization polyoxometalate self-assembly supramolecular chemistry

SCI ; EI

英语

NI期刊 ; NI论文

通讯

Deutsche Forschungsgemeinschaft[STR1164/12, TRR234] ; National Natural Science Foundation of China[U1804253][21771057] ; Henan Normal University[2019PL06] ; Shenzhen Nobel Prize Scientists Laboratory Project[C17213101]

Chemistry

Chemistry, Multidisciplinary

WOS:000532831400035

WILEY-V C H VERLAG GMBH

20201708511731

Boron ; Self assembly ; Oxides ; Nanocapsules

Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Nanotechnology:761 ; Physical Chemistry:801.4 ; Chemical Products Generally:804 ; Solid State Physics:933 ; Materials Science:951

CHEMISTRY

Web of Science

1.Henan Normal Univ, Henan Key Lab Boron Chem & Adv Energy Mat, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China
3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China
4.Ulm Univ, Inst Inorgan Chem, Albert Einstein Allee 11, D-89081 Ulm, Germany
5.Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China

Li, Shujun,Zhou, Yanfang,Ma, Nana,et al. Organoboron-Functionalization Enables the Hierarchical Assembly of Giant Polyoxometalate Nanocapsules[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020,59(22):8537-8540.

Li, Shujun.,Zhou, Yanfang.,Ma, Nana.,Zhang, Jie.,Zheng, Zhiping.,...&Chen, Xuenian.(2020).Organoboron-Functionalization Enables the Hierarchical Assembly of Giant Polyoxometalate Nanocapsules.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,59(22),8537-8540.

Li, Shujun,et al."Organoboron-Functionalization Enables the Hierarchical Assembly of Giant Polyoxometalate Nanocapsules".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 59.22(2020):8537-8540.