南方科技大学知识苑(SUSTech KC): Amide-Based Interface Layer with High Toughness In Situ Building on the Li Metal Anode

题名	Amide-Based Interface Layer with High Toughness In Situ Building on the Li Metal Anode
作者	Wang，Qian 1; Sun，Dandan 1; Zhou，Xiaoyu 1; Wang，Aiping 1; Wang，Da 1; Zhu，Jinlong2 ; Shen，Cai 3; Liu，Yang 1; Guo，Bingkun 1; Wang，Deyu 3
发表日期	2020-06-10
DOI	10.1021/acsami.0c03471
发表期刊	ACS Applied Materials & Interfaces 影响因子和分区
ISSN	1944-8244
EISSN	1944-8252
卷号	12 期号:23页码:25826-25831
摘要	Lithium metal is considered to be the ultimate anode for lithium-ion batteries (LIBs) because of its ultrahigh capacity and lowest electrochemical potential. However, the high reactivity of the lithium metal triggers continuous electrolyte consumption and dendrite growth, resulting in short cycle lifetime and serious safety issues. Massive efforts have been made to stabilize the surface of the lithium metal anode. Here, we propose an amide-based passivation layer to serve as an electrochemically stable and highly tough SEI on the lithium metal anode by in situ generation. The SEI layer presents a high elasticity modulus of 10 GPa and enables stable cycling in 2500 h. Furthermore, based on our strategy, the Li/LiFePO4 cell with a cathode loading of ∼19 mg cm-2 exhibits a long lifespan of 400 cycles. Our approach establishes a meaningful guideline for building a highly strong electrolyte/electrode interface in high-energy density lithium metal batteries.
关键词	additive combination amide-based high toughness lithium metal SEI
相关链接	[Scopus记录]
收录类别	SCI ; EI
语种	英语
学校署名	其他
资助项目	National Key R&D Program of China[2018YFB0104300] ; Science and Technology Commission of Shanghai Municipality[18010500300] ; Guangdong Provincial Key Laboratory of Energy Materials for Electric Power[2018B030322001] ; 111 project[D16002] ; National Natural Science Foundation of China[21503247]
WOS研究方向	Science & Technology - Other Topics ; Materials Science
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000541679900031
出版者	AMER CHEMICAL SOC
EI入藏号	20202708894031
EI主题词	Lithium-ion batteries ; Lithium compounds ; Electrolytes ; Seebeck effect ; Passivation ; Metals ; Anodes
EI分类号	Protection Methods:539.2.1 ; Electricity: Basic Concepts and Phenomena:701.1 ; Electric Batteries and Fuel Cells:702 ; Electron Tubes:714.1 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1
Scopus记录号	2-s2.0-85086345910
来源库	Scopus
引用统计	被引频次[WOS]：8
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/140027
专题	南方科技大学理学院_物理系
作者单位	1.Materials Genome Institute,Shanghai University,China 2.Guangdong Provincial Key Laboratory of Energy Materials for Electric Power,Southern University of Science and Technology,Guangdong Province 518055,China 3.Ningbo Institute of Materials Technology and Engineering,Chinese Academy of Sciences,Ningbo City,Zhejiang Province 315201,China
推荐引用方式 GB/T 7714	Wang，Qian,Sun，Dandan,Zhou，Xiaoyu,et al. Amide-Based Interface Layer with High Toughness In Situ Building on the Li Metal Anode[J]. ACS Applied Materials & Interfaces,2020,12(23):25826-25831.
APA	Wang，Qian.,Sun，Dandan.,Zhou，Xiaoyu.,Wang，Aiping.,Wang，Da.,...&Wang，Deyu.(2020).Amide-Based Interface Layer with High Toughness In Situ Building on the Li Metal Anode.ACS Applied Materials & Interfaces,12(23),25826-25831.
MLA	Wang，Qian,et al."Amide-Based Interface Layer with High Toughness In Situ Building on the Li Metal Anode".ACS Applied Materials & Interfaces 12.23(2020):25826-25831.