南方科技大学知识苑(SUSTech KC): Storage and release of two electrons from an electron-rich carbon-carbon bond: Boron mediated reversible coupling of DMAP and 9-azajulolidine

题名	Storage and release of two electrons from an electron-rich carbon-carbon bond: Boron mediated reversible coupling of DMAP and 9-azajulolidine
作者	Cui，Yunshu; Xiang，Libo; Wang，Junyi; Li，Chunlei; Hao，Wei; Ye，Qing
通讯作者	Ye，Qing
发表日期	2020-06-25
DOI	10.1039/d0cc01575j
发表期刊	CHEMICAL COMMUNICATIONS 影响因子和分区
ISSN	1359-7345
EISSN	1364-548X
卷号	56 期号:50页码:6794-6797
摘要	This manuscript describes the preparation of [{(dpp-bian)BBr}Li(DME)3] (2, dpp-bian = 1,2-bis[(2,6-diisopropylphenyl) imino]acenaphthene) and [{(dpp-bian)BL}+Br-] (5, L = DMAP; 6, L = 9-azajulolidine). The 4,4-coupling of DMAP and 2,2-coupling of 9-azajulolidine can be achieved either by the reaction of 2 with L, or by one-electron reduction of borenium cations 5 and 6. Oxidation of 3 and 4 leads to C-C cleavage and regeneration of 5 and 6. All new compounds have been structurally characterized.
相关链接	[Scopus记录]
收录类别	SCI ; EI ; IC
语种	英语
重要成果	NI论文
学校署名	第一 ; 通讯
资助项目	Science and Technology Innovation Commission of Shenzhen Municipality[JCYJ20170817104802070]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000544928700008
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20202708888464
EI主题词	Carbon ; Positive ions
EI分类号	Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Chemical Products Generally:804
ESI学科分类	CHEMISTRY
Scopus记录号	2-s2.0-85087096068
来源库	Scopus
引用统计	被引频次[WOS]：4
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/140518
专题	理学院_化学系
作者单位	Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China
第一作者单位	化学系
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Cui，Yunshu,Xiang，Libo,Wang，Junyi,et al. Storage and release of two electrons from an electron-rich carbon-carbon bond: Boron mediated reversible coupling of DMAP and 9-azajulolidine[J]. CHEMICAL COMMUNICATIONS,2020,56(50):6794-6797.
APA	Cui，Yunshu,Xiang，Libo,Wang，Junyi,Li，Chunlei,Hao，Wei,&Ye，Qing.(2020).Storage and release of two electrons from an electron-rich carbon-carbon bond: Boron mediated reversible coupling of DMAP and 9-azajulolidine.CHEMICAL COMMUNICATIONS,56(50),6794-6797.
MLA	Cui，Yunshu,et al."Storage and release of two electrons from an electron-rich carbon-carbon bond: Boron mediated reversible coupling of DMAP and 9-azajulolidine".CHEMICAL COMMUNICATIONS 56.50(2020):6794-6797.