南方科技大学知识苑(SUSTech KC): Rhodium(III)-Catalyzed C-H Benzylation of Indole's C3 Position with Aza-o-Quinone Methides

题名	Rhodium(III)-Catalyzed C-H Benzylation of Indole's C3 Position with Aza-o-Quinone Methides
作者	Liu, Ruixing 1; Wei, Yin 1; Shi, Min1,2
通讯作者	Wei, Yin; Shi, Min
发表日期	2020-07-16
DOI	10.1002/adsc.202000613
发表期刊	ADVANCED SYNTHESIS & CATALYSIS 影响因子和分区
ISSN	1615-4150
EISSN	1615-4169
卷号	362 期号:17页码:3649-3654
摘要	In this paper, we report an example of indole's site selective C3 benzylation process through a rhodium(III)-catalyzed indole's C2 activation relay using aza-o-QM as a functionalization reagent, affording the desired products in good yields under mild conditions. The plausible reaction mechanism is proposed on the basis of control and deuterium labeling experiments and the further transformation has been also described.
关键词	rhodium C-H activation quinone methides benzylation indoles
相关链接	[来源记录]
收录类别	SCI ; IC ; CCR
语种	英语
学校署名	通讯
资助项目	Strategic Priority Research Program of the Chinese Academy of Sciences[XDB20000000] ; National Natural Science Foundation of China[21372250][21121062][21302203][20732008][21772037][21772226][21861132014][91956115]
WOS研究方向	Chemistry
WOS类目	Chemistry, Applied ; Chemistry, Organic
WOS记录号	WOS:000548688400001
出版者	WILEY-V C H VERLAG GMBH
来源库	Web of Science
引用统计	被引频次[WOS]：8
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/141433
专题	深圳格拉布斯研究院
作者单位	1.Chinese Acad Sci, Ctr Excellence Mol Synth, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, 354 Fenglin Lu, Shanghai 200032, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518000, Guangdong, Peoples R China
通讯作者单位	深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Liu, Ruixing,Wei, Yin,Shi, Min. Rhodium(III)-Catalyzed C-H Benzylation of Indole's C3 Position with Aza-o-Quinone Methides[J]. ADVANCED SYNTHESIS & CATALYSIS,2020,362(17):3649-3654.
APA	Liu, Ruixing,Wei, Yin,&Shi, Min.(2020).Rhodium(III)-Catalyzed C-H Benzylation of Indole's C3 Position with Aza-o-Quinone Methides.ADVANCED SYNTHESIS & CATALYSIS,362(17),3649-3654.
MLA	Liu, Ruixing,et al."Rhodium(III)-Catalyzed C-H Benzylation of Indole's C3 Position with Aza-o-Quinone Methides".ADVANCED SYNTHESIS & CATALYSIS 362.17(2020):3649-3654.