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题名

Fluorescent chemo-sensors based on "dually smart" optical micro/nano-waveguides lithographically fabricated with AIE composite resins

作者
通讯作者Sun, Yun-Lu; Wu, Chang-Feng; Sun, Hong-Bo
发表日期
2020-07
DOI
发表期刊
ISSN
2051-6347
EISSN
2051-6355
卷号7期号:7页码:1782-1789
摘要
Novel high-performance non-labeled fluoro-sensing micro/nanooptics require lithographically fabricable stimuli-fluorescence transductive materials well-tailored in molecular levels, towards superior processibility, stability, sensitivity, on-chip integration and portability, and real-time and in situ analysis. Here, aggregation-induced-emission fluorophores with oxetane groups (AIEoxes) and their covalently co-crosslinkable epoxy composites are customized for the fabrication of micro/nano-devices via single/multi-photon lithography. The oxetane modification increases the AIEoxe miscibility in the epoxy matrix (doping ratio up to 10 wt%), and consequently improves the as-formed devices' quality, stability, and fluorescence intensity and sensitivity. The multi-color-AIEoxe polymeric micro/nano-devices allow fluorescence-resonance-energy-transfer among AIEoxes, which enables sensitive and specifically spectral detection of VOCs. With the micro/nano-waveguide configuration, solvent-responsive AIE fluorescence and evanescent-field/refractive-index sensing enhance the AIE-fluorescent detection of trace organic solvents in aqueous solutions (detection limit, similar to 0.004% v/v, tetrahydrofuran/water) and their facile integration in functional micro/nano-systems like optofluidics.
相关链接[来源记录]
收录类别
SCI ; EI
语种
英语
学校署名
通讯
资助项目
National Natural Science Foundation of China (NSFC)[2017YFB1104600][61605055][61590930][61825502][81771930] ; Shenzhen Science and Technology Innovation Commission[KQTD20170810111314625] ; Graduate Interdisciplinary Research Fund of Jilin University[10183201832]
WOS研究方向
Chemistry ; Materials Science
WOS类目
Chemistry, Multidisciplinary ; Materials Science, Multidisciplinary
WOS记录号
WOS:000545519100020
出版者
EI入藏号
20202908955615
EI主题词
Evanescent fields ; Fabrication ; Epoxy composites ; Energy transfer
EI分类号
Electricity and Magnetism:701 ; Light/Optics:741.1 ; Materials Science:951
来源库
Web of Science
引用统计
被引频次[WOS]:20
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/141450
专题工学院_生物医学工程系
作者单位
1.Jilin Univ, State Key Lab Integrated Optoelect, Coll Elect Sci & Engn, 2699 Qianjin St, Changchun 130012, Jilin, Peoples R China
2.Univ Michigan, Dept Biomed Engn, Ann Arbor, MI 48109 USA
3.Southern Univ Sci & Technol, Dept Biomed Engn, Shenzhen 510855, Guangdong, Peoples R China
4.Capital Normal Univ, Beijing Key Lab Opt Mat & Photon Devices, Dept Chem, Beijing 100048, Peoples R China
5.Tsinghua Univ, Dept Precis Instrument, State Key Lab Precis Measurement Technol & Instru, Beijing 100084, Peoples R China
通讯作者单位生物医学工程系
推荐引用方式
GB/T 7714
Qian, Meng-Dan,Sun, Yun-Lu,Hu, Zhi-Yong,et al. Fluorescent chemo-sensors based on "dually smart" optical micro/nano-waveguides lithographically fabricated with AIE composite resins[J]. Materials Horizons,2020,7(7):1782-1789.
APA
Qian, Meng-Dan.,Sun, Yun-Lu.,Hu, Zhi-Yong.,Fang, Xiao-Feng.,Zhu, Jin-Long.,...&Sun, Hong-Bo.(2020).Fluorescent chemo-sensors based on "dually smart" optical micro/nano-waveguides lithographically fabricated with AIE composite resins.Materials Horizons,7(7),1782-1789.
MLA
Qian, Meng-Dan,et al."Fluorescent chemo-sensors based on "dually smart" optical micro/nano-waveguides lithographically fabricated with AIE composite resins".Materials Horizons 7.7(2020):1782-1789.
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