y Luminescent tungsten(VI) complexes as photocatalysts for light-driven C-C and C-B bond formation reactions

Yu, Daohong1,2; To, Wai-Pong2; Tong, Glenna So Ming2; Wu, Liang-Liang2; Chan, Kaai-Tung2; Du, Lili2; Phillips, David Lee2; Liu, Yungen1; Che, Chi-Ming1,2,3

2020-07-07

10.1039/d0sc01340d

Chemical Science   影响因子和分区

2041-6520

2041-6539

The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(VI) complex which can be conveniently prepared at the gramscale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.

SCI ; IC ; EI

英语

NI论文

第一 ; 通讯

University Grants Committee Areas of Excellence Scheme[AoE/P-03/08] ; Shenzhen Science and Technology Innovation Committee[JCYJ20170412140251576][JCYJ20180508162429786] ; Hong Kong Research Grants Council[HKU 17330416] ; China Postdoctoral Science Foundation[2018M633043]

Chemistry

Chemistry, Multidisciplinary

WOS:000544484900023

ROYAL SOC CHEMISTRY

20202908934407

Light ; Tungsten compounds ; Redox reactions ; Photochemical reactions

Light/Optics:741.1 ; Chemical Reactions:802.2

Web of Science

1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China
2.Univ Hong Kong, State Key Lab Synthet Chem, HKU CAS Joint Lab New Mat, Dept Chem, Pokfulam Rd, Hong Kong, Peoples R China
3.HKU Shenzhen Inst Res & Innovat Shenzhen, Shenzhen 518055, Guangdong, Peoples R China

Yu, Daohong,To, Wai-Pong,Tong, Glenna So Ming,et al. y Luminescent tungsten(VI) complexes as photocatalysts for light-driven C-C and C-B bond formation reactions[J]. Chemical Science,2020,11(25):6370-6382.

Yu, Daohong.,To, Wai-Pong.,Tong, Glenna So Ming.,Wu, Liang-Liang.,Chan, Kaai-Tung.,...&Che, Chi-Ming.(2020).y Luminescent tungsten(VI) complexes as photocatalysts for light-driven C-C and C-B bond formation reactions.Chemical Science,11(25),6370-6382.

Yu, Daohong,et al."y Luminescent tungsten(VI) complexes as photocatalysts for light-driven C-C and C-B bond formation reactions".Chemical Science 11.25(2020):6370-6382.