Conformationally adaptive macrocycles with flipping aromatic sidewalls

Wang, Xiaoping1; Jia, Fei1,2,3; Yang, Liu-Pan1; Zhou, Hang1; Jiang, Wei1

2020-07-07

10.1039/d0cs00341g

CHEMICAL SOCIETY REVIEWS   影响因子和分区

0306-0012

1460-4744

Conformationally adaptive macrocycles possess multiple well-defined conformations through quickly flipping their aromatic sidewalls. The macrocycles combine the binding power of all the conformations. Upon binding a guest, one or a combination of conformations are selected to achieve the maximized binding affinity. In addition, the complex conformational network is responsive to changes in temperature or solvent. It has been demonstrated that these macrocycles have unique properties in chirality sensing, stimuli-responsive self-assembly, and molecular switches. In this tutorial review, we summarize recent advances on conformationally adaptive macrocycles with an emphasis on our own research. We believe that this class of macrocycles will have a bright future in supramolecular chemistry and beyond.

SCI ; EI

英语

第一 ; 通讯

National Natural Science Foundation of China[21572097][21822104] ; Shenzhen Science and Technology Innovation Committee[JCYJ201805041][65810828] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Shenzhen Nobel Prize Scientists Laboratory Project[C17783101]

Chemistry

Chemistry, Multidisciplinary

WOS:000545930500012

ROYAL SOC CHEMISTRY

20203108992203

Aromatic compounds ; Stereochemistry ; Supramolecular chemistry ; Binding energy ; Chirality

Chemistry:801 ; Physical Chemistry:801.4 ; Organic Compounds:804.1 ; Atomic and Molecular Physics:931.3

CHEMISTRY

Web of Science

1.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China
2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China
3.Free Univ Berlin, Inst Chem & Biochem, Arnimallee 20, D-14195 Berlin, Germany

Wang, Xiaoping,Jia, Fei,Yang, Liu-Pan,et al. Conformationally adaptive macrocycles with flipping aromatic sidewalls[J]. CHEMICAL SOCIETY REVIEWS,2020,49(13):4176-4188.

Wang, Xiaoping,Jia, Fei,Yang, Liu-Pan,Zhou, Hang,&Jiang, Wei.(2020).Conformationally adaptive macrocycles with flipping aromatic sidewalls.CHEMICAL SOCIETY REVIEWS,49(13),4176-4188.

Wang, Xiaoping,et al."Conformationally adaptive macrocycles with flipping aromatic sidewalls".CHEMICAL SOCIETY REVIEWS 49.13(2020):4176-4188.