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题名

Core-shell structured polyethylene glycol functionalized graphene for energy-storage polymer dielectrics: Combined mechanical and dielectric performances

作者
通讯作者Li,Yuchao; Liao,Chengzhu; Liao,Yaozu
发表日期
2020-10-20
DOI
发表期刊
ISSN
0266-3538
EISSN
1879-1050
卷号199
摘要

Polydispersed graphene was synthesized by grafting a thin layer of water-soluble amine functionalized polyethylene glycol monomethyl ether (PEG-NH). PEG-NH functionalized graphene (PEG@rGO) was then introduced into epoxy resin via a facile solution mixing method. Fourier-transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA) verified that PEG was successfully grafted to the surface of graphene. The obtained PEG@rGO showed excellent dispersibility in solvents when compared to pristine graphene. As a “core-shell” filler, PEG@rGO filled epoxy nanocomposites displayed improved dielectric constant and reduced dielectric loss, exhibiting potential applications in energy storage capacitors. The mechanical strength and final decomposition temperature were also simultaneously increased.

关键词
相关链接[Scopus记录]
收录类别
SCI ; EI
语种
英语
学校署名
通讯
资助项目
Natural Science Foundation of Shandong Province[ZR2019MB053][ZR2019QEM009] ; Natural Science Foundation of China[51603098][21703096][51873036][51673039] ; Shenzhen ST Project Grant[JCYJ20150630145302228]
WOS研究方向
Materials Science
WOS类目
Materials Science, Composites
WOS记录号
WOS:000576141400003
出版者
EI入藏号
20203008969781
EI主题词
Energy storage ; Grafting (chemical) ; Polyethylene oxides ; Polyethylenes ; Shells (structures) ; Graphene ; Thermogravimetric analysis ; Dielectric materials ; Fourier transform infrared spectroscopy ; Dielectric losses ; Polyethylene glycols ; X ray photoelectron spectroscopy ; Epoxy resins
EI分类号
Structural Members and Shapes:408.2 ; Energy Storage:525.7 ; Dielectric Materials:708.1 ; Nanotechnology:761 ; Chemistry:801 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Organic Polymers:815.1.1 ; Temperature Measurements:944.6
ESI学科分类
MATERIALS SCIENCE
Scopus记录号
2-s2.0-85088218010
来源库
Scopus
引用统计
被引频次[WOS]:17
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/141554
专题工学院_材料科学与工程系
作者单位
1.School of Materials Science and Engineering,Liaocheng University,Liaocheng,252059,China
2.Centre for Advanced Materials Technology (CAMT),School of Aerospace,Mechanical and Mechatronic Engineering,The University of Sydney,Sydney,2006,Australia
3.Department of Materials Science and Engineering,Southern University of Science and Technology,Shenzhen,518055,China
4.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering,Donghua University,Shanghai,201620,China
通讯作者单位材料科学与工程系
推荐引用方式
GB/T 7714
Li,Yuchao,Bi,Xueqing,Wang,Shuangshuang,et al. Core-shell structured polyethylene glycol functionalized graphene for energy-storage polymer dielectrics: Combined mechanical and dielectric performances[J]. COMPOSITES SCIENCE AND TECHNOLOGY,2020,199.
APA
Li,Yuchao.,Bi,Xueqing.,Wang,Shuangshuang.,Zhan,Yanhu.,Liu,Hong Yuan.,...&Liao,Yaozu.(2020).Core-shell structured polyethylene glycol functionalized graphene for energy-storage polymer dielectrics: Combined mechanical and dielectric performances.COMPOSITES SCIENCE AND TECHNOLOGY,199.
MLA
Li,Yuchao,et al."Core-shell structured polyethylene glycol functionalized graphene for energy-storage polymer dielectrics: Combined mechanical and dielectric performances".COMPOSITES SCIENCE AND TECHNOLOGY 199(2020).
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