南方科技大学知识苑(SUSTech KC): Kinetic Studies for the Reaction of syn-CH3CHOO with CF3CH═CH2

题名	Kinetic Studies for the Reaction of syn-CH3CHOO with CF3CH═CH2
作者	Zhou，Xiaohu 1,2,3; Liu，Yiqiang 3,4; Chen，Yang 3,5,6; Li，Xinyong 1; Xiao，Chunlei 3; Dong，Wenrui 3; Yang，Xueming3,7
通讯作者	Dong，Wenrui; Yang，Xueming
发表日期	2020-07-30
DOI	10.1021/acs.jpca.0c03534
发表期刊	JOURNAL OF PHYSICAL CHEMISTRY A 影响因子和分区
ISSN	1089-5639
EISSN	1520-5215
卷号	124 期号:30页码:6125-6132
摘要	Hydrofluoroolefins (HFOs, CxF2x+1CH═CH2) have great potential to replace hydrofluorocarbons (HFCs) as refrigerants. Here the kinetics for the reaction of syn-CH3CHOO with CF3CH═CH2 (HFO-1243zf), the simplest of HFOs, have been studied in a flash photolysis flow reactor at a total pressure of 50 Torr, by using the OH laser-induced fluorescence (LIF) method. The bimolecular reaction rate coefficients were measured at temperatures ranging from 283 to 318 K. A weak positive temperature dependence was observed, with an activation energy of 1.41 ± 0.12 kcal mol-1. At 298 K, the measured rate coefficient was (2.42 ± 0.51) × 10-14 cm3 s-1, in the vicinity of the previously reported upper limit value for the reaction of CH2OO with CF3CH═CH2.
相关链接	[Scopus记录]
收录类别	SCI ; EI
语种	英语
学校署名	通讯
资助项目	Strategic Priority Research Program of Chinese Academy of Sciences[XDB17000000] ; National Natural Science Foundation of China (NSFC)[21873098] ; International Partnership Program of Chinese Academy of Sciences[121421KYSB20170012] ; Chemical Dynamics Research Center[21688102] ; LiaoNing Revitalization Talents Program[XLYC1807248]
WOS研究方向	Chemistry ; Physics
WOS类目	Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS记录号	WOS:000558657400001
出版者	AMER CHEMICAL SOC
EI入藏号	20203509114019
EI主题词	Temperature distribution ; Reaction kinetics ; Photolysis ; Activation energy
EI分类号	Thermodynamics:641.1 ; Laser Applications:744.9 ; Chemical Reactions:802.2
ESI学科分类	CHEMISTRY
Scopus记录号	2-s2.0-85089611366
来源库	Scopus
引用统计	被引频次[WOS]：5
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/153326
专题	理学院_化学系
作者单位	1.Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education),School of Environmental Science and Technology,Dalian University of Technology,Dalian,116024,China 2.Zhang Dayu School of Chemistry,Dalian University of Technology,Dalian,116024,China 3.State Key Laboratory of Molecular Reaction Dynamics,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,116023,China 4.Key Laboratory of Materials Modification by Laser,Ion and Electron Beams (Ministry of Education),School of Physics,Dalian University of Technology,Dalian,116024,China 5.Key Laboratory of Chemical Lasers,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,116023,China 6.University of Chinese Academy of Sciences,100049,China 7.Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China
通讯作者单位	化学系
推荐引用方式 GB/T 7714	Zhou，Xiaohu,Liu，Yiqiang,Chen，Yang,et al. Kinetic Studies for the Reaction of syn-CH3CHOO with CF3CH═CH2[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2020,124(30):6125-6132.
APA	Zhou，Xiaohu.,Liu，Yiqiang.,Chen，Yang.,Li，Xinyong.,Xiao，Chunlei.,...&Yang，Xueming.(2020).Kinetic Studies for the Reaction of syn-CH3CHOO with CF3CH═CH2.JOURNAL OF PHYSICAL CHEMISTRY A,124(30),6125-6132.
MLA	Zhou，Xiaohu,et al."Kinetic Studies for the Reaction of syn-CH3CHOO with CF3CH═CH2".JOURNAL OF PHYSICAL CHEMISTRY A 124.30(2020):6125-6132.