Rhodium(III)-Catalyzed Cross Coupling of Sulfoxonium Ylides and 1,3-Diynes to Produce Naphthol-Indole Derivatives: An AreneorthoC-H Activation/Annulation Cascade

Liu, Ruixing1; Wei, Yin1; Shi, Min1,2

2020-09-16

10.1002/cctc.202001315

ChemCatChem   影响因子和分区

1867-3880

1867-3899

Synthesis of naphthol-indoles starting from easily available 1,3-diynes and sulfoxonium ylides via Rh-III-catalyzed C-H activation/hydroamination cascade process in a one pot manner has been developed. The reaction proceeds through a Rh-III-catalyzed areneorthoC-H activation and silver-catalyzed hydroamination cascade to afford a variety of C2 position functionalized indoles in good yields with broad substrate scope and good functional group tolerance.

rhodium silver C-H activation sulfoxonium ylides naphthol-indole

SCI ; EI

英语

通讯

Strategic Priority Research Program of the Chinese Academy of Sciences[XDB20000000] ; National Natural Science Foundation of China[21372250][21121062][21302203][20732008][21772037][21772226][21861132014][91956115]

Chemistry

Chemistry, Physical

WOS:000569491900001

WILEY-V C H VERLAG GMBH

20203809213183

Naphthol ; Rhodium compounds ; Polycyclic aromatic hydrocarbons ; Rhodium ; Catalysis ; Naphthalene ; Silver

Precious Metals:547.1 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Organic Compounds:804.1

Web of Science

1.Chinese Acad Sci, Shanghai Inst Organ Chem, Univ Chinese Acad Sci, State Key Lab Organometall Chem,Ctr Excellence Mo, 345 Lingling Lu, Shanghai 200032, Peoples R China
2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518000, Guangdong, Peoples R China

Liu, Ruixing,Wei, Yin,Shi, Min. Rhodium(III)-Catalyzed Cross Coupling of Sulfoxonium Ylides and 1,3-Diynes to Produce Naphthol-Indole Derivatives: An AreneorthoC-H Activation/Annulation Cascade[J]. ChemCatChem,2020,12(23):5903-5906.

Liu, Ruixing,Wei, Yin,&Shi, Min.(2020).Rhodium(III)-Catalyzed Cross Coupling of Sulfoxonium Ylides and 1,3-Diynes to Produce Naphthol-Indole Derivatives: An AreneorthoC-H Activation/Annulation Cascade.ChemCatChem,12(23),5903-5906.

Liu, Ruixing,et al."Rhodium(III)-Catalyzed Cross Coupling of Sulfoxonium Ylides and 1,3-Diynes to Produce Naphthol-Indole Derivatives: An AreneorthoC-H Activation/Annulation Cascade".ChemCatChem 12.23(2020):5903-5906.