题名 | Synthesis of P-chiral phosphine compounds by palladium-catalyzed C-P coupling reactions |
作者 | |
通讯作者 | Yuan, Jia; Yu, Guang-Ao; Che, Chi-Ming |
发表日期 | 2020-10-11
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DOI | |
发表期刊 | |
ISSN | 1359-7345
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EISSN | 1364-548X
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卷号 | 56期号:79页码:11775-11778 |
摘要 | An efficient C-P coupling reaction of enantiopure tert-butylmethylphosphine-boranes with aryl and heteroaryl halides is developed by using Pd(OAc)(2)/dppf as a catalyst, affording a series of (S) or (R)-Pchiral phosphines in moderate to high yields and with ee values up to 99% ee. Moreover, the reaction time could be reduced from 72 h to 6 h with increased ee values under microwave irradiation. |
相关链接 | [来源记录] |
收录类别 | |
语种 | 英语
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重要成果 | NI论文
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学校署名 | 其他
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资助项目 | National Natural Science Foundation of China[21472060][21772058][21072071]
; 111 Project[B17019]
; self-determined research funds of CCNU from the colleges' basic research and operation of MOE[CCNU17CG0011][CCNU17KYZHSY07][CCNU18KYZHSY06]
; China Postdoctoral Science Foundation[2018M632898]
; Shenzhen Science and Technology Innovation Commission[JCYJ20170412140251576]
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WOS研究方向 | Chemistry
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WOS类目 | Chemistry, Multidisciplinary
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WOS记录号 | WOS:000575366000037
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出版者 | |
EI入藏号 | 20204109336665
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EI主题词 | Boron compounds
; Phosphorus compounds
; Palladium
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EI分类号 | Precious Metals:547.1
; Electromagnetic Waves:711
|
ESI学科分类 | CHEMISTRY
|
来源库 | Web of Science
|
引用统计 |
被引频次[WOS]:11
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成果类型 | 期刊论文 |
条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/199586 |
专题 | 理学院_化学系 |
作者单位 | 1.Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China 2.Cent China Normal Univ, Coll Chem, Chem Biol Ctr, Wuhan 430079, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 4.Univ Hong Kong, State Key Lab Synthet Chem, Pokfulam Rd, Hong Kong, Peoples R China 5.Univ Hong Kong, Dept Chem, Pokfulam Rd, Hong Kong, Peoples R China |
推荐引用方式 GB/T 7714 |
Wang, Cuiying,Yue, Chang-Duo,Yuan, Jia,et al. Synthesis of P-chiral phosphine compounds by palladium-catalyzed C-P coupling reactions[J]. CHEMICAL COMMUNICATIONS,2020,56(79):11775-11778.
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APA |
Wang, Cuiying.,Yue, Chang-Duo.,Yuan, Jia.,Zheng, Jia-Lian.,Zhang, Ying.,...&Che, Chi-Ming.(2020).Synthesis of P-chiral phosphine compounds by palladium-catalyzed C-P coupling reactions.CHEMICAL COMMUNICATIONS,56(79),11775-11778.
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MLA |
Wang, Cuiying,et al."Synthesis of P-chiral phosphine compounds by palladium-catalyzed C-P coupling reactions".CHEMICAL COMMUNICATIONS 56.79(2020):11775-11778.
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条目包含的文件 | 条目无相关文件。 |
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