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题名

Synthesis of P-chiral phosphine compounds by palladium-catalyzed C-P coupling reactions

作者
通讯作者Yuan, Jia; Yu, Guang-Ao; Che, Chi-Ming
发表日期
2020-10-11
DOI
发表期刊
ISSN
1359-7345
EISSN
1364-548X
卷号56期号:79页码:11775-11778
摘要
An efficient C-P coupling reaction of enantiopure tert-butylmethylphosphine-boranes with aryl and heteroaryl halides is developed by using Pd(OAc)(2)/dppf as a catalyst, affording a series of (S) or (R)-Pchiral phosphines in moderate to high yields and with ee values up to 99% ee. Moreover, the reaction time could be reduced from 72 h to 6 h with increased ee values under microwave irradiation.
相关链接[来源记录]
收录类别
SCI ; EI ; IC ; CCR
语种
英语
重要成果
NI论文
学校署名
其他
资助项目
National Natural Science Foundation of China[21472060][21772058][21072071] ; 111 Project[B17019] ; self-determined research funds of CCNU from the colleges' basic research and operation of MOE[CCNU17CG0011][CCNU17KYZHSY07][CCNU18KYZHSY06] ; China Postdoctoral Science Foundation[2018M632898] ; Shenzhen Science and Technology Innovation Commission[JCYJ20170412140251576]
WOS研究方向
Chemistry
WOS类目
Chemistry, Multidisciplinary
WOS记录号
WOS:000575366000037
出版者
EI入藏号
20204109336665
EI主题词
Boron compounds ; Phosphorus compounds ; Palladium
EI分类号
Precious Metals:547.1 ; Electromagnetic Waves:711
ESI学科分类
CHEMISTRY
来源库
Web of Science
引用统计
被引频次[WOS]:11
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/199586
专题理学院_化学系
作者单位
1.Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China
2.Cent China Normal Univ, Coll Chem, Chem Biol Ctr, Wuhan 430079, Peoples R China
3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
4.Univ Hong Kong, State Key Lab Synthet Chem, Pokfulam Rd, Hong Kong, Peoples R China
5.Univ Hong Kong, Dept Chem, Pokfulam Rd, Hong Kong, Peoples R China
推荐引用方式
GB/T 7714
Wang, Cuiying,Yue, Chang-Duo,Yuan, Jia,et al. Synthesis of P-chiral phosphine compounds by palladium-catalyzed C-P coupling reactions[J]. CHEMICAL COMMUNICATIONS,2020,56(79):11775-11778.
APA
Wang, Cuiying.,Yue, Chang-Duo.,Yuan, Jia.,Zheng, Jia-Lian.,Zhang, Ying.,...&Che, Chi-Ming.(2020).Synthesis of P-chiral phosphine compounds by palladium-catalyzed C-P coupling reactions.CHEMICAL COMMUNICATIONS,56(79),11775-11778.
MLA
Wang, Cuiying,et al."Synthesis of P-chiral phosphine compounds by palladium-catalyzed C-P coupling reactions".CHEMICAL COMMUNICATIONS 56.79(2020):11775-11778.
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