Theoretical Understandings of Graphene-based Metal Single-Atom Catalysts: Stability and Catalytic Performance

Zhuo，Hong Ying1,2; Zhang，Xin2; Liang，Jin Xia3; Yu，Qi4; Xiao，Hai1; Li，Jun1,3

2020-11-11

10.1021/acs.chemrev.0c00818

CHEMICAL REVIEWS   影响因子和分区

0009-2665

1520-6890

Research on heterogeneous single-atom catalysts (SACs) has become an emerging frontier in catalysis science because of their advantages in high utilization of noble metals, precisely identified active sites, high selectivity, and tunable activity. Graphene, as a one-atom-thick two-dimensional carbon material with unique structural and electronic properties, has been reported to be a superb support for SACs. Herein, we provide an overview of recent progress in investigations of graphene-based SACs. Among the large number of publications, we will selectively focus on the stability of metal single-atoms (SAs) anchored on different sites of graphene support and the catalytic performances of graphene-based SACs for different chemical reactions, including thermocatalysis and electrocatalysis. We will summarize the fundamental understandings on the electronic structures and their intrinsic connection with catalytic properties of graphene-based SACs, and also provide a brief perspective on the future design of efficient SACs with graphene and graphene-like materials.

SCI ; EI

英语

ESI高被引

其他

National Natural Science Foundation of China[22033005][91645203][21590792][21573286]

Chemistry

Chemistry, Multidisciplinary

WOS:000588271100011

AMER CHEMICAL SOC

20204709517819

Atoms ; Electronic structure ; Electronic properties ; Catalyst selectivity ; Chemical stability ; Electrocatalysis ; Catalyst activity

Nanotechnology:761 ; Chemistry:801 ; Electrochemistry:801.4.1 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Atomic and Molecular Physics:931.3

CHEMISTRY

2-s2.0-85096080076

Scopus

1.Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education,Tsinghua University,100084,China
2.State Key Laboratory of Heavy Oil Processing,College of Chemical Engineering,China University of Petroleum,102249,China
3.Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China
4.School of Materials Science and Engineering,Institute of Graphene at Shaanxi Key Laboratory of Catalysis,Shaanxi University of Technology,Hanzhong,723001,China

Zhuo，Hong Ying,Zhang，Xin,Liang，Jin Xia,et al. Theoretical Understandings of Graphene-based Metal Single-Atom Catalysts: Stability and Catalytic Performance[J]. CHEMICAL REVIEWS,2020,120(21):12315-12341.

Zhuo，Hong Ying,Zhang，Xin,Liang，Jin Xia,Yu，Qi,Xiao，Hai,&Li，Jun.(2020).Theoretical Understandings of Graphene-based Metal Single-Atom Catalysts: Stability and Catalytic Performance.CHEMICAL REVIEWS,120(21),12315-12341.

Zhuo，Hong Ying,et al."Theoretical Understandings of Graphene-based Metal Single-Atom Catalysts: Stability and Catalytic Performance".CHEMICAL REVIEWS 120.21(2020):12315-12341.