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题名

Trimetallic Zeolitic imidazolite framework-derived Co nanoparticles@CoFe-nitrogen-doped porous carbon as bifunctional electrocatalysts for Zn-air battery

作者
通讯作者Liu, Kaiyu; Liu, Chen; Lu, Zhouguang
发表日期
2021-03-15
DOI
发表期刊
ISSN
0021-9797
EISSN
1095-7103
卷号586页码:621-629
摘要
Searching for high active, low cost and durable catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) remains challenge in developing metal-air battery cathodes. Herein, we proposed a novel bifunctional catalyst derived from the pyrolysis of Co/Fe/Zn trimetallic zeolitic imidazolite framework. The obtained Co@CoFe0.01-N-C catalyst displays desirable activity for both ORR and OER (E-1/2 = 0.844 V, E-j=10 = 1.654 V). The Zn-air battery equipped with Co@CoFe0.01-N-C catalyst on the cathode exhibits a high peak power density of 174.1 mW cm(2), which is much superior than that of commercial 20% Pt/C (87.6 mW cm(2)). Significantly, the designed Co@CoFe0.01-N-C presents an outstanding stability for over 100 h in rechargeable Zn-air battery. (C) 2020 Elsevier Inc. All rights reserved.
关键词
相关链接[来源记录]
收录类别
SCI ; EI
语种
英语
学校署名
通讯
资助项目
Basic Research Project of the Science and Technology Innovation Commission of Shenzhen["JCYJ20190809115413414","JCYJ20170412153139454"] ; National Natural Science Foundation of China[21671096,21905180] ; Guangdong Provincial Key Laboratory of Energy Materials for Electric Power[2018B030322001] ; Shenzhen Peacock Plan[KQTD2016022620054656]
WOS研究方向
Chemistry
WOS类目
Chemistry, Physical
WOS记录号
WOS:000606833200004
出版者
EI入藏号
20204709501282
EI主题词
Electrocatalysts ; Electrolytic reduction ; Metal nanoparticles ; Carbon ; Oxygen reduction reaction ; Metal-Organic Frameworks ; Porous materials ; Catalyst activity ; Cathodes ; Doping (additives) ; Oxygen ; Nitrogen
EI分类号
Metallurgy:531.1 ; Ore Treatment:533.1 ; Secondary Batteries:702.1.2 ; Nanotechnology:761 ; Electrochemistry:801.4.1 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1 ; Materials Science:951
ESI学科分类
CHEMISTRY
来源库
Web of Science
引用统计
被引频次[WOS]:32
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/209469
专题工学院_材料科学与工程系
作者单位
1.Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Chem Power Sources, Changsha 410083, Peoples R China
2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Energy Mat Elect Power, Shenzhen Key Lab Hydrogen Energy, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
3.Shenzhen Univ, Coll Mat Sci & Engn, Guangdong Res Ctr Interfacial Engn Funct Mat, Shenzhen 518060, Peoples R China
第一作者单位材料科学与工程系
通讯作者单位材料科学与工程系
推荐引用方式
GB/T 7714
Hao, Rui,Chen, Jingjing,Wang, Zhenyu,et al. Trimetallic Zeolitic imidazolite framework-derived Co nanoparticles@CoFe-nitrogen-doped porous carbon as bifunctional electrocatalysts for Zn-air battery[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2021,586:621-629.
APA
Hao, Rui.,Chen, Jingjing.,Wang, Zhenyu.,Huang, Yanping.,Liu, Penggao.,...&Lu, Zhouguang.(2021).Trimetallic Zeolitic imidazolite framework-derived Co nanoparticles@CoFe-nitrogen-doped porous carbon as bifunctional electrocatalysts for Zn-air battery.JOURNAL OF COLLOID AND INTERFACE SCIENCE,586,621-629.
MLA
Hao, Rui,et al."Trimetallic Zeolitic imidazolite framework-derived Co nanoparticles@CoFe-nitrogen-doped porous carbon as bifunctional electrocatalysts for Zn-air battery".JOURNAL OF COLLOID AND INTERFACE SCIENCE 586(2021):621-629.
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