南方科技大学知识苑(SUSTech KC): Enantioselective Hydrogenation of Endocyclic Enones: the Solution to a Historical Problem(dagger)

题名	Enantioselective Hydrogenation of Endocyclic Enones: the Solution to a Historical Problem(dagger)
作者	Lang, Qiwei 1; Yang, Huaxin1 ; Gu, Guoxian 1; Feng, Qiang 1; Wen, Jialin1,2 ; Zhang, Xumu1
通讯作者	Wen, Jialin; Zhang, Xumu
发表日期	2021-02-01
DOI	10.1002/cjoc.202000617
发表期刊	CHINESE JOURNAL OF CHEMISTRY 影响因子和分区
ISSN	1001-604X
EISSN	1614-7065
摘要	["Main observation and conclusion","The enantioselective hydrogenation of endocyclic enones has been a historical problem for homogeneous catalysis. We herein report an efficient method to reduce endocyclic enones with molecular hydrogen. Catalyzed by a rhodium/Zhaophos complex, a variety of enones with five-, six- or seven-member ring were hydrogenated with high enantioselectivity (92%-99% ee). Excellent chemo- and enantioselectivity demonstrated this method was successfully applied in the enantioselective hydrogenation of citral to produce enantio-enriched citronellal."]
关键词	Asymmetric catalysis Hydrogenation Cyclic enone Rhodium Citral reduction
相关链接	[来源记录]
收录类别	SCI
语种	英语
学校署名	第一 ; 通讯
资助项目	Science, Technology and Innovation Commission of Shenzhen["KQTD20150717103157174","JCYJ20170817104350391"] ; National Natural Science Foundation of China[21801118] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000621424000001
出版者	WILEY-V C H VERLAG GMBH
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：7
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/220950
专题	理学院_化学系前沿与交叉科学研究院
作者单位	1.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Dept Chem, 1088 Xueyuan Rd, Shenzhen 515055, Guangdong, Peoples R China 2.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, 1088 Xueyuan Rd, Shenzhen 515055, Guangdong, Peoples R China
第一作者单位	化学系
通讯作者单位	化学系; 前沿与交叉科学研究院
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Lang, Qiwei,Yang, Huaxin,Gu, Guoxian,et al. Enantioselective Hydrogenation of Endocyclic Enones: the Solution to a Historical Problem(dagger)[J]. CHINESE JOURNAL OF CHEMISTRY,2021.
APA	Lang, Qiwei,Yang, Huaxin,Gu, Guoxian,Feng, Qiang,Wen, Jialin,&Zhang, Xumu.(2021).Enantioselective Hydrogenation of Endocyclic Enones: the Solution to a Historical Problem(dagger).CHINESE JOURNAL OF CHEMISTRY.
MLA	Lang, Qiwei,et al."Enantioselective Hydrogenation of Endocyclic Enones: the Solution to a Historical Problem(dagger)".CHINESE JOURNAL OF CHEMISTRY (2021).