| 题名 | Catalytic Enantioselective Synthesis of Spirooxindoles by Oxidative Rearrangement of Indoles |
| 作者 | |
| 通讯作者 | Li, Pengfei; Sun, Jianwei |
| 发表日期 | 2021-02-01
|
| DOI | |
| 发表期刊 | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| 卷号 | 60页码:5871-5875 |
| 摘要 | Oxidative rearrangement of indoles to access oxindoles has been used as a key step in complex molecule synthesis. We report a catalytic enantioselective variant of this transformation by chiral phosphoric acid catalysis, providing rapid access to a range of enantioenriched spirooxindoles. The high enantioselectivity is controlled by dynamic kinetic resolution. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI期刊
|
| 学校署名 | 通讯
|
| 资助项目 | National Natural Science Foundation of China[91956114]
; Research Grants Council of Hong Kong[16302617,16302318]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
|
| WOS记录号 | WOS:000613447400001
|
| 出版者 | |
| EI入藏号 | 20210609878871
|
| EI主题词 | Chelation
; Phosphoric acid
; Stereochemistry
; Synthesis (chemical)
|
| EI分类号 | Chemistry:801
; Physical Chemistry:801.4
; Chemical Reactions:802.2
; Inorganic Compounds:804.2
|
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：38
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/221016 |
| 专题 | 深圳格拉布斯研究院 理学院_化学系 |
| 作者单位 | 1.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Clear Water Bay, Hong Kong, Peoples R China 2.Southern Univ Sci & Technol, Coll Sci, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Coll Sci, Guangdong Prov Key Lab Catalysis, Dept Chem, Shenzhen 518055, Peoples R China |
| 第一作者单位 | 深圳格拉布斯研究院; 化学系 |
| 通讯作者单位 | 深圳格拉布斯研究院; 化学系 |
| 推荐引用方式 GB/T 7714 |
Qian, Chenxiao,Li, Pengfei,Sun, Jianwei. Catalytic Enantioselective Synthesis of Spirooxindoles by Oxidative Rearrangement of Indoles[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2021,60:5871-5875.
|
| APA |
Qian, Chenxiao,Li, Pengfei,&Sun, Jianwei.(2021).Catalytic Enantioselective Synthesis of Spirooxindoles by Oxidative Rearrangement of Indoles.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,60,5871-5875.
|
| MLA |
Qian, Chenxiao,et al."Catalytic Enantioselective Synthesis of Spirooxindoles by Oxidative Rearrangement of Indoles".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 60(2021):5871-5875.
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| 条目包含的文件 | 条目无相关文件。 | |||||
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