| 题名 | Formation and Characterization of BeFe(CO)(4)(-) Anion with Beryllium-Iron Bonding |
| 作者 | |
| 通讯作者 | Hu, Han-Shi; Zhou, Mingfei |
| 发表日期 | 2021-03-01
|
| DOI | |
| 发表期刊 | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| 卷号 | 60期号:17页码:9334-9338 |
| 摘要 | Heteronuclear BeFe(CO)(4)(-) anion complex is generated in the gas phase, which is detected by mass-selected infrared photodissociation spectroscopy in the carbonyl stretching frequency region. The complex is characterized to have a Be-Fe bonded Be-Fe(CO)(4)(-) structure with C-3v symmetry and all of the four carbonyl ligands bonded on the iron center. Quantum chemical studies indicate that the complex has a quite short Be-Fe bond. Besides one electron-sharing sigma bond, there are two additional, albeit weak, Be <- Fe(CO)(4)(-) dative pi bonding interactions. The findings imply that metal-metal bonding between s-block and transition metals is viable under suitable coordination environment. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI论文
|
| 学校署名 | 其他
|
| 资助项目 | National Natural Science Foundation[21688102,22033005,91645203,21590792]
; Science Challenge Project[TZ2016004]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
|
| WOS记录号 | WOS:000627040300001
|
| 出版者 | |
| EI入藏号 | 20211110072437
|
| EI主题词 | Beryllium
; Iron
; Photodissociation
; Quantum chemistry
|
| EI分类号 | Iron:545.1
; Nonferrous Metals and Alloys:549
; Physical Chemistry:801.4
|
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：20
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/221128 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Fudan Univ, Shanghai Key Lab Mol Catalysts & Innovat Mat, Collaborat Innovat Ctr Chem Energy Mat, Dept Chem, Shanghai 200438, Peoples R China 2.Tsinghua Univ, Minist Educ, Dept Chem, Beijing 100084, Peoples R China 3.Tsinghua Univ, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China 4.Southern Univ Sci & Technol, Sch Sci, Dept Chem, Shenzhen 518055, Peoples R China |
| 推荐引用方式 GB/T 7714 |
Wang, Guanjun,Zhao, Jing,Hu, Han-Shi,et al. Formation and Characterization of BeFe(CO)(4)(-) Anion with Beryllium-Iron Bonding[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2021,60(17):9334-9338.
|
| APA |
Wang, Guanjun,Zhao, Jing,Hu, Han-Shi,Li, Jun,&Zhou, Mingfei.(2021).Formation and Characterization of BeFe(CO)(4)(-) Anion with Beryllium-Iron Bonding.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,60(17),9334-9338.
|
| MLA |
Wang, Guanjun,et al."Formation and Characterization of BeFe(CO)(4)(-) Anion with Beryllium-Iron Bonding".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 60.17(2021):9334-9338.
|
| 条目包含的文件 | 条目无相关文件。 | |||||
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