南方科技大学知识苑(SUSTech KC): Selective dopant segregation modulates mesoscale reaction kinetics in layered transition metal oxide

题名	Selective dopant segregation modulates mesoscale reaction kinetics in layered transition metal oxide
作者	Qian，Guannan 1,2; Huang，Hai 2,5; Hou，Fuchen4,6 ; Wang，Weina 1; Wang，Yong 1; Lin，Junhao4 ; Lee，Sang Jun 2; Yan，Hanfei 3; Chu，Yong S.3; Pianetta，Piero 2; Huang，Xiaojing 3; Ma，Zi Feng 1; Li，Linsen 1; Liu，Yijin 2; Qian，Guannan 7,8; Huang，Hai 8,11; Hou，Fuchen10,12 ; Wang，Weina 7; Wang，Yong 7; Lin，Junhao10 ; Lee，Sang Jun 8; Yan，Hanfei 9; Chu，Yong S.9; Pianetta，Piero 8; Huang，Xiaojing 9; Ma，Zi Feng 7; Li，Linsen 7; Liu，Yijin 8; Qian，Guannan 13,14; Huang，Hai 14,17; Hou，Fuchen16,18 ; Wang，Weina 13; Wang，Yong 13; Lin，Junhao16 ; Lee，Sang Jun 14; Yan，Hanfei 15; Chu，Yong S.15; Pianetta，Piero 14; Huang，Xiaojing 15; Ma，Zi Feng 13; Li，Linsen 13; Liu，Yijin 14
通讯作者	Huang，Xiaojing; Huang，Xiaojing; Huang，Xiaojing
共同第一作者	Qian，Guannan; Huang，Hai; Hou，Fuchen; Qian，Guannan; Huang，Hai; Hou，Fuchen; Qian，Guannan; Huang，Hai; Hou，Fuchen
发表日期	2021-06-01
DOI	10.1016/j.nanoen.2021.105926
发表期刊	Nano Energy 影响因子和分区
ISSN	2211-2855
卷号	84
摘要	Incorporation of foreign elements into the cathode material is broadly adopted by both academia and industry to improve the battery performance. The lack of an in-depth understanding for the underlying mechanism, however, makes it a largely try-and-error process with unsatisfactory efficiency and effectiveness. This is particularly true for the electrochemical reaction kinetics that is heterogeneous over a broad range of length scales and is determined collectively by the cathode's electronic structure, lattice configuration, and micro-morphology. Here we unveiled a facet-dependent dopant segregation effect in Zr-modified single-crystal LiNiCoMnO cathode. By forming kinetically favored corners on the cathode particles, the presence of a trace amount of Zr critically modulates the mesoscale reaction kinetics. Our findings suggest that a delicately controlled dopant distribution is a viable strategy for designing the next-generation battery cathode with superior structural and chemical robustness.
关键词	Layered Cathodes Lithium Diffusion Mesoscale Kinetics Transition Metal Oxides
相关链接	[Scopus记录]
收录类别	SCI ; EI
语种	英语
学校署名	共同第一 ; 其他
WOS记录号	WOS:000649703500001
EI入藏号	20210910001806
EI主题词	Association Reactions ; Cathodes ; Cobalt Compounds ; Electric Batteries ; Electronic Structure ; Kinetics ; Lithium Compounds ; Manganese Compounds ; Nickel Compounds ; Segregation (Metallography) ; Single Crystals ; Transition Metal Oxides ; Transition Metals ; Zirconium Compounds
EI分类号	Metallurgy And Metallography:531 ; Metallography:531.2 ; Electric Batteries:702.1 ; Chemical Reactions:802.2 ; Classical Physics ; Quantum Theory ; Relativity:931 ; Crystalline Solids:933.1
Scopus记录号	2-s2.0-85101633923
来源库	Scopus
引用统计	被引频次[WOS]：51
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/221471
专题	理学院_物理系工学院_材料科学与工程系
作者单位	1.Department of Chemical Engineering,Shanghai Electrochemical Energy Device Research Center (SEED),Shanghai Jiao Tong University,Shanghai,200240,China 2.Stanford Synchrotron Radiation Lightsource,SLAC National Accelerator Laboratory,Menlo Park,94025,United States 3.National Synchrotron Light Source II,Brookhaven National Laboratory,Upton,11973,United States 4.Department of Physics and Shenzhen Key Laboratory of for Advanced Quantum Functional Materials and Devices,Southern University of Science and Technology,Shenzhen,518055,China 5.Department of Materials Science,Fudan University,Shanghai,200433,China 6.Key Laboratory of Quantum Information,University of Science and Technology of China,Hefei,230026,China 7.Department of Chemical Engineering,Shanghai Electrochemical Energy Device Research Center (SEED),Shanghai Jiao Tong University,Shanghai,200240,China 8.Stanford Synchrotron Radiation Lightsource,SLAC National Accelerator Laboratory,Menlo Park,94025,United States 9.National Synchrotron Light Source II,Brookhaven National Laboratory,Upton,11973,United States 10.Department of Physics and Shenzhen Key Laboratory of for Advanced Quantum Functional Materials and Devices,Southern University of Science and Technology,Shenzhen,518055,China 11.Department of Materials Science,Fudan University,Shanghai,200433,China 12.Key Laboratory of Quantum Information,University of Science and Technology of China,Hefei,230026,China 13.Department of Chemical Engineering,Shanghai Electrochemical Energy Device Research Center (SEED),Shanghai Jiao Tong University,Shanghai,200240,China 14.Stanford Synchrotron Radiation Lightsource,SLAC National Accelerator Laboratory,Menlo Park,94025,United States 15.National Synchrotron Light Source II,Brookhaven National Laboratory,Upton,11973,United States 16.Department of Physics and Shenzhen Key Laboratory of for Advanced Quantum Functional Materials and Devices,Southern University of Science and Technology,Shenzhen,518055,China 17.Department of Materials Science,Fudan University,Shanghai,200433,China 18.Key Laboratory of Quantum Information,University of Science and Technology of China,Hefei,230026,China
推荐引用方式 GB/T 7714	Qian，Guannan,Huang，Hai,Hou，Fuchen,et al. Selective dopant segregation modulates mesoscale reaction kinetics in layered transition metal oxide[J]. Nano Energy,2021,84.
APA	Qian，Guannan.,Huang，Hai.,Hou，Fuchen.,Wang，Weina.,Wang，Yong.,...&Liu，Yijin.(2021).Selective dopant segregation modulates mesoscale reaction kinetics in layered transition metal oxide.Nano Energy,84.
MLA	Qian，Guannan,et al."Selective dopant segregation modulates mesoscale reaction kinetics in layered transition metal oxide".Nano Energy 84(2021).

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