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题名

Organocatalytic enantioselective [2 + 4]-annulation of γ-substituted allenoates withN-acyldiazenes for the synthesis of optically active 1,3,4-oxadiazines

作者
通讯作者Li,Xuechen; Li,Pengfei
发表日期
2021-02-28
DOI
发表期刊
ISSN
1477-0520
EISSN
1477-0539
卷号19期号:8页码:1727-1731
摘要

An enantioselective [2 + 4]-annulation of γ-substituted allenoates withN-acyldiazenes has been developed for the first time. In the presence of anl-proline-derived DMAP analogue, the annulation proceeded smoothly to afford a broad range of 1,3,4-oxadiazine derivatives in good to excellent yields with high stereoselectivities.;An enantioselective [2 + 4]-annulation of γ-substituted allenoates withN-acyldiazenes has been developed for the first time. In the presence of anl-proline-derived DMAP analogue, the annulation proceeded smoothly to afford a broad range of 1,3,4-oxadiazine derivatives in good to excellent yields with high stereoselectivities.;An enantioselective [2 + 4]-annulation of γ-substituted allenoates withN-acyldiazenes has been developed for the first time. In the presence of anl-proline-derived DMAP analogue, the annulation proceeded smoothly to afford a broad range of 1,3,4-oxadiazine derivatives in good to excellent yields with high stereoselectivities.

相关链接[Scopus记录]
收录类别
SCI ; IC ; CCR ; EI
语种
英语
学校署名
第一 ; 通讯
资助项目
National Natural Science Foundation of China[21871128] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
WOS研究方向
Chemistry
WOS类目
Chemistry, Organic
WOS记录号
WOS:000625235100004
出版者
EI入藏号
20211010049918
EI主题词
Chemistry ; Positive ions
EI分类号
Chemistry:801 ; Physical Chemistry:801.4
ESI学科分类
CHEMISTRY
Scopus记录号
2-s2.0-85102064377
来源库
Scopus
引用统计
被引频次[WOS]:12
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/221613
专题理学院_化学系
理学院
深圳格拉布斯研究院
作者单位
1.Shenzhen Grubbs Institute and Department of Chemistry,Guangdong Provincial Key Laboratory of Catalysis,College of Science,Southern University of Science and Technology,Shenzhen,518055,China
2.Department of Chemistry,State Key Lab of Synthetic Chemistry,University of Hong Kong,Hong Kong
第一作者单位化学系;  深圳格拉布斯研究院;  理学院
通讯作者单位化学系;  深圳格拉布斯研究院;  理学院
第一作者的第一单位化学系;  深圳格拉布斯研究院;  理学院
推荐引用方式
GB/T 7714
Guo,Xing,Chen,Xuling,Cheng,Yuyu,et al. Organocatalytic enantioselective [2 + 4]-annulation of γ-substituted allenoates withN-acyldiazenes for the synthesis of optically active 1,3,4-oxadiazines[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2021,19(8):1727-1731.
APA
Guo,Xing,Chen,Xuling,Cheng,Yuyu,Chang,Xiaoyong,Li,Xuechen,&Li,Pengfei.(2021).Organocatalytic enantioselective [2 + 4]-annulation of γ-substituted allenoates withN-acyldiazenes for the synthesis of optically active 1,3,4-oxadiazines.ORGANIC & BIOMOLECULAR CHEMISTRY,19(8),1727-1731.
MLA
Guo,Xing,et al."Organocatalytic enantioselective [2 + 4]-annulation of γ-substituted allenoates withN-acyldiazenes for the synthesis of optically active 1,3,4-oxadiazines".ORGANIC & BIOMOLECULAR CHEMISTRY 19.8(2021):1727-1731.
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