题名 | A PEGylated N-heterocyclic carbene-gold(i) complex: An efficient catalyst for cyclization reaction in water |
作者 | |
通讯作者 | Zhang,Xumu |
发表日期 | 2021-03-21
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DOI | |
发表期刊 | |
ISSN | 2052-4110
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EISSN | 2052-4129
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卷号 | 8期号:6页码:1216-1222 |
摘要 | Here we describe an efficient method for the synthesis of a PEGylated N-heterocyclic carbene(NHC)-gold(i) complex. This PEGylated NHC-gold(i) complex exhibited high reactivity and regio-selectivity in the cyclization of various alkynoic acids and cascade reaction of tryptamine and alkynoic acids in water. A systematic study of double cyclization of dialkynoic acids to construct spiro enol lactones was first reported. Importantly, this water-soluble catalyst could be recycled seven times while maintaining good catalytic activity. This journal is |
相关链接 | [Scopus记录] |
收录类别 | |
语种 | 英语
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学校署名 | 通讯
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资助项目 | National Natural Science Foundation of China["NSFC 91856203",21472159]
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WOS研究方向 | Chemistry
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WOS类目 | Chemistry, Organic
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WOS记录号 | WOS:000631592900014
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出版者 | |
EI入藏号 | 20211310140216
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EI主题词 | Aromatic compounds
; Catalyst activity
; Cyclization
; Synthesis (chemical)
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EI分类号 | Chemical Reactions:802.2
; Chemical Agents and Basic Industrial Chemicals:803
; Chemical Products Generally:804
; Organic Compounds:804.1
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来源库 | Web of Science
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引用统计 |
被引频次[WOS]:11
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成果类型 | 期刊论文 |
条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/222669 |
专题 | 理学院_化学系 |
作者单位 | 1.Department of Chemistry,State Key Laboratory of Synthetic Chemistry,University of Hong Kong,Pokfulam Road,Hong Kong 2.Department of Chemistry,Southern University of Science and Technology,Shenzhen,518000,China |
第一作者单位 | 化学系 |
通讯作者单位 | 化学系 |
推荐引用方式 GB/T 7714 |
Lin,Bijin,Zhang,Xumu,Zhou,Cong Ying,et al. A PEGylated N-heterocyclic carbene-gold(i) complex: An efficient catalyst for cyclization reaction in water[J]. Organic Chemistry Frontiers,2021,8(6):1216-1222.
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APA |
Lin,Bijin,Zhang,Xumu,Zhou,Cong Ying,&Che,Chi Ming.(2021).A PEGylated N-heterocyclic carbene-gold(i) complex: An efficient catalyst for cyclization reaction in water.Organic Chemistry Frontiers,8(6),1216-1222.
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MLA |
Lin,Bijin,et al."A PEGylated N-heterocyclic carbene-gold(i) complex: An efficient catalyst for cyclization reaction in water".Organic Chemistry Frontiers 8.6(2021):1216-1222.
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