Asymmetric Synthesis of Silicon-Stereogenic Monohydrosilanes by Dehydrogenative C-H Silylation

Yuan，Wei; You，Lijun; Lin，Weidong; Ke，Jie; Li，Yingzi; He，Chuan

2021-02-19

10.1021/acs.orglett.1c00029

ORGANIC LETTERS   影响因子和分区

1523-7060

1523-7052

An asymmetric synthesis of silicon-stereogenic monohydrosilanes by rhodium-catalyzed dehydrogenative C-H silylation is developed. The process is suitable for the synthesis of various asymmetrically trisubstituted 1H-benzosiloles and 1H-benzosilolometallocenes in good yields with excellent chemo-, regio-, and stereocontrol. These selected silicon-stereogenic 1H-benzosilole compounds exhibit bright blue fluorescence and CPL (circular polarized luminescence) signals, which could be attractive to practitioners of materials science.

SCI

英语

NI论文

第一 ; 通讯

National Natural Science Foundation of China[21901104] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]

Chemistry

Chemistry, Organic

WOS:000629002000039

AMER CHEMICAL SOC

CHEMISTRY

2-s2.0-85100968400

Scopus

Shenzhen Grubbs Institute and Department of Chemistry,Guangdong Provincial Key Laboratory of Catalysis,Southern University of Science and Technology,Shenzhen,518055,China

Yuan，Wei,You，Lijun,Lin，Weidong,et al. Asymmetric Synthesis of Silicon-Stereogenic Monohydrosilanes by Dehydrogenative C-H Silylation[J]. ORGANIC LETTERS,2021,23(4):1367-1372.

Yuan，Wei,You，Lijun,Lin，Weidong,Ke，Jie,Li，Yingzi,&He，Chuan.(2021).Asymmetric Synthesis of Silicon-Stereogenic Monohydrosilanes by Dehydrogenative C-H Silylation.ORGANIC LETTERS,23(4),1367-1372.

Yuan，Wei,et al."Asymmetric Synthesis of Silicon-Stereogenic Monohydrosilanes by Dehydrogenative C-H Silylation".ORGANIC LETTERS 23.4(2021):1367-1372.