Single-atom-nickel photocatalytic site-selective sulfonation of enamides to access amidosulfones dagger

Yang, Jianjing1; Sun, Zongzhao2; Yan, Kelu1; Dong, Haozhe1; Dong, Hongyan1; Cui, Jiakai1; Gong, Xutao1; Han, Shilin1; Huang, Limin2; Wen, Jiangwei1

2021-03-01

10.1039/d1gc00379h

GREEN CHEMISTRY   影响因子和分区

1463-9262

1463-9270

Single-atom photocatalysis as an important organic transformation strategy has received increasing attention, with the performances largely depending on the design of catalysts. This protocol involves initially the fabrication of a single-atom photocatalyst Ni/TiO2 for the visible-light-induced site-selective sulfonation of enamides to give amidosulfones with 36 examples up to 99% yield. The experimental results show that this single-atom photocatalyst Ni/TiO2 can achieve site-selective sulfonation of enamide to construct alpha-amidosulfones and beta-propionamidosulfones under visible light. Importantly, such a single-atom photocatalysis-based synthesis system exhibits favorable recyclability, high turnover number (up to 18 963), excellent tolerance of functional groups, and can be easily scaled up with good efficiency.

SCI ; EI

英语

通讯

National Natural Science Foundation of China[21902083] ; Natural Science Foundation of Shandong Province, Shandong, P. R. China[ZR2020QB130] ; College Students Innovation and Entrepreneurship Training Project of Shandong Province[S202010446066] ; Guangdong Innovative and Entrepreneurial Research Team Program[2016ZT06N532] ; Guangdong Provincial Key Laboratory of Materials for Electric Power[2018B030322001] ; Talent Program Foundation of Qufu Normal University[6132,6125]

Chemistry ; Science & Technology - Other Topics

Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology

WOS:000632981800001

ROYAL SOC CHEMISTRY

20211610225734

Light ; Nickel ; Photocatalysis ; Sulfonation

Nickel:548.1 ; Light/Optics:741.1 ; Chemical Reactions:802.2 ; Atomic and Molecular Physics:931.3

CHEMISTRY

Web of Science

1.Qufu Normal Univ, Coll Chem & Chem Engn, Inst Med & Mat Appl Technol, Qufu 273165, Shandong, Peoples R China
2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China

Yang, Jianjing,Sun, Zongzhao,Yan, Kelu,et al. Single-atom-nickel photocatalytic site-selective sulfonation of enamides to access amidosulfones dagger[J]. GREEN CHEMISTRY,2021,23:2756-2762.

Yang, Jianjing.,Sun, Zongzhao.,Yan, Kelu.,Dong, Haozhe.,Dong, Hongyan.,...&Wen, Jiangwei.(2021).Single-atom-nickel photocatalytic site-selective sulfonation of enamides to access amidosulfones dagger.GREEN CHEMISTRY,23,2756-2762.

Yang, Jianjing,et al."Single-atom-nickel photocatalytic site-selective sulfonation of enamides to access amidosulfones dagger".GREEN CHEMISTRY 23(2021):2756-2762.