南方科技大学知识苑(SUSTech KC): Atom Transfer Radical Addition to Styrenes with Thiosulfonates Enabled by Synergetic Copper/Photoredox Catalysis

题名	Atom Transfer Radical Addition to Styrenes with Thiosulfonates Enabled by Synergetic Copper/Photoredox Catalysis
作者	Zhou, Xin 1,2,3 ; Peng, Zhiyuan2,3 ; Wang, Peng George4 ; Liu, Qingchao 1; Jia, Tiezheng2,3,5
通讯作者	Liu, Qingchao; Jia, Tiezheng
发表日期	2021-02-05
DOI	10.1021/acs.orglett.0c04254
发表期刊	ORGANIC LETTERS 影响因子和分区
ISSN	1523-7060
EISSN	1523-7052
卷号	23 期号:3
摘要	A synergetic copper/photoredox catalyzed ATRA of styrenes and thiosulfonates is developed. Besides aryl ethylenes, the challenging alpha-substituted styrenes were employed to construct the benzylic quaternary carbon centers. Owing to the mild conditions as well as the high level of substrate compability, this ATRA could be applied to derivatize bioactive natural products in late stage, and to install fluorophores across alkenes. The mechanistic studies reveal sulfonyl radicals as the key intermediate in the transformation.
相关链接	[来源记录]
收录类别	SCI
语种	英语
重要成果	NI论文
学校署名	通讯
资助项目	Science and Technology Innovation Commission of Shenzhen Municipality[JCYJ20180302180256215] ; Shenzhen Nobel Prize Scientists Laboratory Project[C17783101] ; Guang-dong Provincial Key Laboratory of Catalysis[2020B121201002] ; National Natural Science Foundation of China[22078263,
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000629001700080
出版者	AMER CHEMICAL SOC
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：36
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/225997
专题	理学院_化学系南方科技大学医学院深圳格拉布斯研究院南方科技大学医学院_药理学系
作者单位	1.Northwest Univ, Coll Chem Engn, Dept Pharmaceut Engn, Xian 710069, Shanxi, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China 3.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Guangdong, Peoples R China 4.Southern Univ Sci & Technol, Sch Med, Shenzhen 518055, Peoples R China 5.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
第一作者单位	化学系; 深圳格拉布斯研究院; 南方科技大学
通讯作者单位	化学系; 深圳格拉布斯研究院; 南方科技大学
推荐引用方式 GB/T 7714	Zhou, Xin,Peng, Zhiyuan,Wang, Peng George,et al. Atom Transfer Radical Addition to Styrenes with Thiosulfonates Enabled by Synergetic Copper/Photoredox Catalysis[J]. ORGANIC LETTERS,2021,23(3).
APA	Zhou, Xin,Peng, Zhiyuan,Wang, Peng George,Liu, Qingchao,&Jia, Tiezheng.(2021).Atom Transfer Radical Addition to Styrenes with Thiosulfonates Enabled by Synergetic Copper/Photoredox Catalysis.ORGANIC LETTERS,23(3).
MLA	Zhou, Xin,et al."Atom Transfer Radical Addition to Styrenes with Thiosulfonates Enabled by Synergetic Copper/Photoredox Catalysis".ORGANIC LETTERS 23.3(2021).