Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A(2)B(6)-type POSS Monomer

Fan, Lin-Feng1,2; Hou, Cui-Ling3; Wang, Xing1,2; Yan, Li-Tang3; Wu, De-Cheng1,4

2021-07-01

10.1007/s10118-021-2598-8

CHINESE JOURNAL OF POLYMER SCIENCE   影响因子和分区

0256-7679

1439-6203

The growing demands of supramolecular hyperbranched polymers integrating noncovalent interaction and unique topological structure merits had received considerable interest in the fabrication of novel materials for advanced applications. Herein, we prepared A(2)B(6)-type POSS-containing supramolecular hyperbranched polymers with multiple morphologies including lamellar-like, branched, hollow, core-shell and porous spherical structures through regulating self-assembling monomer concentrations and solvent polarities. The incorporation of appropriate emulative guest molecules would further trigger morphological transformations (such as vesicles and spherical micelles) by synergistic effects of unique POSS aggregation ability, supramolecular complexations and hydrophilic-hydrophobic interactions. Thus, this facile and universal strategy may enable a modular nanofabrication of supramolecular hyperbranched polymers with diversiform topological structure and sophisticated multifunctionality for their potential applications.

POSS Host-guest interaction A(2)B(6)-type monomer Supramolecular polymer Morphological transformation

SCI ; EI

英语

通讯

Ministry of Science and Technology of China[2020YFA0908900] ; National Natural Science Foundation of China[51973226,21935011,21725403,81871782] ; Youth Innovation Promotion Association CAS[2019031]

Polymer Science

Polymer Science

WOS:000672985700001

SPRINGER

20212910643026

Chlorine containing polymers ; Hydrophobicity ; Ions ; Micelles ; Monomers ; Polymer blends ; Solvents ; Supramolecular chemistry ; Topology

Colloid Chemistry:801.3 ; Physical Chemistry:801.4 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Polymeric Materials:815.1 ; Polymer Products:817.1 ; Combinatorial Mathematics, Includes Graph Theory, Set Theory:921.4 ; Physical Properties of Gases, Liquids and Solids:931.2

CHEMISTRY

Web of Science

1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Tsinghua Univ, Dept Chem Engn, State Key Lab Chem Engn, Beijing 100049, Peoples R China
4.Southern Univ Sci & Technol, Dept Biomed Engn, Shenzhen 518055, Guangdong, Peoples R China

Fan, Lin-Feng,Hou, Cui-Ling,Wang, Xing,et al. Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A(2)B(6)-type POSS Monomer[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2021,39:1562-1571.

Fan, Lin-Feng,Hou, Cui-Ling,Wang, Xing,Yan, Li-Tang,&Wu, De-Cheng.(2021).Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A(2)B(6)-type POSS Monomer.CHINESE JOURNAL OF POLYMER SCIENCE,39,1562-1571.

Fan, Lin-Feng,et al."Tunable Multiple Morphological Transformation of Supramolecular Hyperbranched Polymers Based on an A(2)B(6)-type POSS Monomer".CHINESE JOURNAL OF POLYMER SCIENCE 39(2021):1562-1571.