南方科技大学知识苑(SUSTech KC): Spin and valence isomerism in cyanide-bridged {FeIII2MII} (M = Fe and Co) clusters

题名	Spin and valence isomerism in cyanide-bridged {FeIII2MII} (M = Fe and Co) clusters
作者	Zhao，Xin Hua1 ; Shao，Dong1 ; Chen，Jia Tao1 ; Liu，Min 2; Li，Tao1 ; Yang，Jiong1 ; Zhang，Yuan Zhu1
通讯作者	Zhang，Yuan Zhu
发表日期	2021-07-28
DOI	10.1039/d1dt01298c
发表期刊	DALTON TRANSACTIONS 影响因子和分区
ISSN	1477-9226
EISSN	1477-9234
卷号	50 期号:28页码:9768-9774
摘要	Two cyanide-bridged V-shaped isostructural trinuclear complexes [{(Tp)Fe(CN)}M(bztpen)]·Sol (M = Fe, Sol = CHOH·3HO,1; M = Co, Sol = 2CHOH·2HO,2; bztpen =N-benzyl-N,N′,N′-tris(2-methylpyridyl)ethylenediamine; Tp = hydrotris(3,5-dimethylpyrazolyl)borate) were synthesized and characterized. The bztpen ligand serves as a tetradentate capping ligand around the inner metal ion, leaving one pyridyl group intact. Complex1exhibits a spin crossover (SCO) behavior between the {FeFeFe} and {FeFeFe} spin isomers, while2shows both thermally- and photo-induced electron-transfer coupled spin transition (ETCST) property between the {FeCoFe} and {FeCoFe} valence isomers. The total entropy changes for1and2between their corresponding two electronic states were found to be very close with the values of 87.46 and 84.49 J molK, respectively, indicating the comparable thermal energy barriers necessary for either an SCO or ETCST event for such a given system. Furthermore, both complexes undergo desolvation-induced irreversible and sharp magnetic change at high temperatures.
相关链接	[Scopus记录]
收录类别	SCI ; EI
语种	英语
学校署名	第一 ; 通讯
WOS记录号	WOS:000665862300001
EI入藏号	20213010679120
EI主题词	Cyanides ; Electron transport properties ; Iron ; Isomers ; Ligands ; Metal ions ; Sols ; Stereochemistry
EI分类号	Metallurgy:531.1 ; Iron:545.1 ; Chemistry:801 ; Physical Chemistry:801.4 ; Chemical Products Generally:804 ; Inorganic Compounds:804.2
ESI学科分类	CHEMISTRY
Scopus记录号	2-s2.0-85111068680
来源库	Scopus
引用统计	被引频次[WOS]：16
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/242069
专题	理学院_化学系
作者单位	1.Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China 2.College of Nuclear Science and Technology,University of South China,Hengyang,421001,China
第一作者单位	化学系
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Zhao，Xin Hua,Shao，Dong,Chen，Jia Tao,et al. Spin and valence isomerism in cyanide-bridged {FeIII2MII} (M = Fe and Co) clusters[J]. DALTON TRANSACTIONS,2021,50(28):9768-9774.
APA	Zhao，Xin Hua.,Shao，Dong.,Chen，Jia Tao.,Liu，Min.,Li，Tao.,...&Zhang，Yuan Zhu.(2021).Spin and valence isomerism in cyanide-bridged {FeIII2MII} (M = Fe and Co) clusters.DALTON TRANSACTIONS,50(28),9768-9774.
MLA	Zhao，Xin Hua,et al."Spin and valence isomerism in cyanide-bridged {FeIII2MII} (M = Fe and Co) clusters".DALTON TRANSACTIONS 50.28(2021):9768-9774.