Interfacial Interactions between Co-Based Cocatalysts and Semiconducting Light Absorbers for Solar-Light-Driven Redox Reactions

Guo，Qing1,2; Feng，Xiyuan3; Zhang，Z. Conrad2; Huang，Limin4

2021

10.1002/solr.202100234

Solar RRL   影响因子和分区

2367-198X

Solar-light-driven redox reactions, such as water splitting for hydrogen and oxygen evolution, and CO reduction, have recently shown great promise toward solar-to-fuel conversion. Herein, the recent achievements in establishing interfacial interactions between cocatalysts and semiconducting light absorbers to improve the efficiency of these reactions are focused on. Four kinds of interactions are summarized to clarify the accelerated photogenerated charge carrier kinetics, thereby resulting in enhanced activity of these redox reactions. Especially, the coordination interaction formed by chemical linkage seems to be more preferred because of a well-provided tunnel for charge transfer. The extended applications of these interfacial interactions to other challenging reactions, such as N fixation and organic synthesis, are also predicted.

Co-based cocatalysts heterogeneous photocatalysis interfacial interactions redox reactions solar-to-chemical conversion

SCI ; EI

英语

第一 ; 通讯

WOS:000664892000001

20212610550377

Charge transfer ; Hydrogen fuels ; Redox reactions

Gas Fuels:522 ; Solar Energy and Phenomena:657.1 ; Chemical Reactions:802.2 ; Chemical Products Generally:804

2-s2.0-85108311511

Scopus

1.Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China
2.State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,116023,China
3.Department of Materials Science and Engineering,Southern University of Science and Technology,Shenzhen,518055,China
4.Shenzhen Key Laboratory of Solid State Batteries,Guangdong Provincial Key Laboratory of Energy Materials for Electric Power,Guangdong-Hong Kong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices,Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China

Guo，Qing,Feng，Xiyuan,Zhang，Z. Conrad,et al. Interfacial Interactions between Co-Based Cocatalysts and Semiconducting Light Absorbers for Solar-Light-Driven Redox Reactions[J]. Solar RRL,2021,5.

Guo，Qing,Feng，Xiyuan,Zhang，Z. Conrad,&Huang，Limin.(2021).Interfacial Interactions between Co-Based Cocatalysts and Semiconducting Light Absorbers for Solar-Light-Driven Redox Reactions.Solar RRL,5.

Guo，Qing,et al."Interfacial Interactions between Co-Based Cocatalysts and Semiconducting Light Absorbers for Solar-Light-Driven Redox Reactions".Solar RRL 5(2021).