Naphthobox: a selective molecular box for planar aromatic cations

Pang, Xin-Yu; Zhou, Hang; Yao, Huan; Jiang, Wei1

2021-08-01

10.1039/d1qo00819f

Organic Chemistry Frontiers   影响因子和分区

2052-4129

A naphthol-based molecular box (so called "napthobox") was reported. The naphthobox has a well-preorganized and electron-rich cavity, which is able to selectively recognize planar aromatic cations by cationMIDLINE HORIZONTAL ELLIPSIS pi interactions and C-HMIDLINE HORIZONTAL ELLIPSIS pi interactions. In addition, a charge-transfer system responsive to strong coordination anions was constructed based on the complex between naphthobox and tropylium, which may be used to distinguish the coordination ability of anions by the naked eye.

SCI ; EI

英语

通讯

National Natural Science Foundation of China[21772083,21822104] ; Shenzhen Science and Technology Innovation Committee[JCYJ20180504165810828] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]

Chemistry

Chemistry, Organic

WOS:000681726000001

ROYAL SOC CHEMISTRY

20214010985699

Aromatic compounds ; Coordination reactions ; Naphthol ; Positive ions

Chemical Reactions:802.2 ; Organic Compounds:804.1

Web of Science

1.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen Grubbs Inst, Xueyuan Blvd 1088, Shenzhen 518055, Peoples R China
2.Southern Univ Sci & Technol, Dept Chem, Xueyuan Blvd 1088, Shenzhen 518055, Peoples R China

Pang, Xin-Yu,Zhou, Hang,Yao, Huan,et al. Naphthobox: a selective molecular box for planar aromatic cations[J]. Organic Chemistry Frontiers,2021,8:5265-5270.

Pang, Xin-Yu,Zhou, Hang,Yao, Huan,&Jiang, Wei.(2021).Naphthobox: a selective molecular box for planar aromatic cations.Organic Chemistry Frontiers,8,5265-5270.

Pang, Xin-Yu,et al."Naphthobox: a selective molecular box for planar aromatic cations".Organic Chemistry Frontiers 8(2021):5265-5270.