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题名

Effective and Rapid Removal of Polar Organic Micropollutants from Water by Amide Naphthotube-Crosslinked Polymers

作者
通讯作者Jiang, Wei
发表日期
2021-08-01
DOI
发表期刊
ISSN
1433-7851
EISSN
1521-3773
卷号60页码:21404-21411
摘要
It is challenging to remove polar organic micropollutants from water through adsorption-mediated processes. Macrocycle-crosslinked polymers were recently shown to be effective adsorbents for nonpolar or charged organic micropollutants through specific host-guest binding, but are rarely used for the treatment of neutral and polar organic micropollutants. This is due to the challenge of recognizing polar molecules in water by macrocyclic hosts. In this research, we report two amide naphthotube-crosslinked polymers which can effectively and rapidly adsorb a wide scope of polar organic micropollutants from water through biomimetic molecular recognition. Amide naphthotubes possess hydrogen bonding sites in their deep hydrophobic cavities and can effectively bind polar organic micropollutants in water through the hydrophobic effects and shielded hydrogen bonds. The cross-linked polymers containing amide naphthotubes are even able to remove a complex mixture of organic micropollutants from water and the used materials can be easily regenerated through washing with MeOH or EtOH. This research provides a solution for the treatment of polar organic micropollutants by using biomimetic molecular recognition in water.
关键词
相关链接[来源记录]
收录类别
SCI ; EI
语种
英语
重要成果
NI期刊
学校署名
第一 ; 通讯
资助项目
National Natural Science Foundation of China[21772083,21822104] ; Shenzhen Science and Technology Innovation Committee[JCYJ20180504165810828] ; Guangdong High-Level Personnel of Special Support Program[2019TX05C157] ; Shenzhen "Pengcheng Scholar" and Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
WOS研究方向
Chemistry
WOS类目
Chemistry, Multidisciplinary
WOS记录号
WOS:000686499000001
出版者
EI入藏号
20213410801645
EI主题词
Amides ; Biomimetics ; Chlorine containing polymers ; Crosslinking ; Functional polymers ; Hydrogen bonds ; Hydrophobicity ; Molecular recognition
EI分类号
Biotechnology:461.8 ; Chemistry:801 ; Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Organic Compounds:804.1 ; Polymeric Materials:815.1 ; Organic Polymers:815.1.1 ; Physical Properties of Gases, Liquids and Solids:931.2
ESI学科分类
CHEMISTRY
来源库
Web of Science
引用统计
被引频次[WOS]:46
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/242965
专题理学院_化学系
前沿与交叉科学研究院
深圳格拉布斯研究院
作者单位
1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Guangdong Prov Key Lab Catalysis, Xueyuan Blvd 1088, Shenzhen 518055, Peoples R China
2.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Xueyuan Blvd 1088, Shenzhen 518055, Peoples R China
第一作者单位化学系;  深圳格拉布斯研究院;  前沿与交叉科学研究院
通讯作者单位化学系;  深圳格拉布斯研究院;  前沿与交叉科学研究院
第一作者的第一单位化学系;  深圳格拉布斯研究院
推荐引用方式
GB/T 7714
Yang, Liu-Pan,Ke, Hua,Yao, Huan,et al. Effective and Rapid Removal of Polar Organic Micropollutants from Water by Amide Naphthotube-Crosslinked Polymers[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2021,60:21404-21411.
APA
Yang, Liu-Pan,Ke, Hua,Yao, Huan,&Jiang, Wei.(2021).Effective and Rapid Removal of Polar Organic Micropollutants from Water by Amide Naphthotube-Crosslinked Polymers.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,60,21404-21411.
MLA
Yang, Liu-Pan,et al."Effective and Rapid Removal of Polar Organic Micropollutants from Water by Amide Naphthotube-Crosslinked Polymers".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 60(2021):21404-21411.
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