Magnetic AgNPs/Fe3O4@chitosan/PVA nanocatalyst for fast one-pot green synthesis of propargylamine and triazole derivatives

Ghasemi, Kousar1; Darroudi, Mahdieh2,3; Rahimi, Marjan4; Rouh, Hossein5; Gupta, Anju R.6; Cheng, Chun7; Amini, Abbas8,9

2021-07-01

10.1039/d1nj02354c

NEW JOURNAL OF CHEMISTRY   影响因子和分区

1144-0546

1369-9261

A new green magnetic nanocatalyst was introduced for one-pot fast synthesis of propargylamine and triazole derivatives. Chitosan bio-polymeric chains were functionalized with polyvinyl alcohol (PVA) and then templated with silver nanoparticles (AgNPs) and magnetic Fe3O4 to obtain the AgNPs/Fe3O4@chitosan/PVA composite. Spectral and analytical examinations were conducted using X-ray diffraction, Fourier transform-infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, vibrating sample magnetometry, and energy-dispersive X-ray spectroscopy for understanding the structural, morphological and physiochemical features of the obtained magnetic nanocomposite and the homogeneous distribution of AgNPs on the surface of nanocomposite with Fe3O4 nucleus. The AgNPs/Fe3O4@chitosan/PVA nanocatalyst was used in the synthesis of biologically active compounds such as propargylamine and triazole derivatives through multicomponent A(3)-coupling and click reactions. The catalyzed products were obtained in high yields under ambient conditions through a low-cost, facile, one-pot, and environmentally friendly protocol. The reusability of the heterogeneous magnetic catalyst was also confirmed up to six cycles without any significant loss in the catalytic activity, as well as easy separation of the catalyst.

SCI ; EI

英语

其他

Australian College of Kuwait["IRC-2020/2021-SOE-ME-PR05","PR06"]

Chemistry

Chemistry, Multidisciplinary

WOS:000686741400001

ROYAL SOC CHEMISTRY

20213810913444

Bioactivity ; Catalyst activity ; Chitosan ; Condensation reactions ; Energy dispersive spectroscopy ; Fourier transform infrared spectroscopy ; Green Synthesis ; High resolution transmission electron microscopy ; Nanocatalysts ; Nanocomposites ; Reusability ; Scanning electron microscopy ; Silver nanoparticles

Medicine and Pharmacology:461.6 ; Magnetism: Basic Concepts and Phenomena:701.2 ; Optical Devices and Systems:741.3 ; Nanotechnology:761 ; Chemistry:801 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1 ; Solid State Physics:933

CHEMISTRY

Web of Science

1.Univ Mazandaran, Fac Chem, Dept Organ Chem, Babolsar, Iran
2.Turkish Germen Univ, Fac Sci, Dept Energy Sci & Technol, Istanbul, Turkey
3.Mashhad Univ Med Sci, Sch Sci, Dept Med Biotechnol & Nanotechnol, Mashhad, Razavi Khorasan, Iran
4.Islamic Azad Univ, Dept Chem, Mashhad Branch, Mashhad, Razavi Khorasan, Iran
5.Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA
6.Univ Toledo, Dept Mech Engn Ind & Mfg Engn, 2801 W Bancroft St, Toledo, OH 43606 USA
7.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen, Peoples R China
8.Australian Coll Kuwait, Dept Mech Engn, Safat 13015, Kuwait
9.Western Sydney Univ, Ctr Infrastruct Engn, Kingswood Campus,Bld Z,Locked Bag 1797, Penrith, NSW 2751, Australia

Ghasemi, Kousar,Darroudi, Mahdieh,Rahimi, Marjan,et al. Magnetic AgNPs/Fe3O4@chitosan/PVA nanocatalyst for fast one-pot green synthesis of propargylamine and triazole derivatives[J]. NEW JOURNAL OF CHEMISTRY,2021,45:16119-16130.

Ghasemi, Kousar.,Darroudi, Mahdieh.,Rahimi, Marjan.,Rouh, Hossein.,Gupta, Anju R..,...&Amini, Abbas.(2021).Magnetic AgNPs/Fe3O4@chitosan/PVA nanocatalyst for fast one-pot green synthesis of propargylamine and triazole derivatives.NEW JOURNAL OF CHEMISTRY,45,16119-16130.

Ghasemi, Kousar,et al."Magnetic AgNPs/Fe3O4@chitosan/PVA nanocatalyst for fast one-pot green synthesis of propargylamine and triazole derivatives".NEW JOURNAL OF CHEMISTRY 45(2021):16119-16130.