Anti-perovskite materials for energy storage batteries

Deng, Zhi1; Ni, Dixing1; Chen, Diancheng1; Bian, Ying1; Li, Shuai1,2; Wang, Zhaoxiang3,4; Zhao, Yusheng1,2

2021-09-01

10.1002/inf2.12252

INFOMAT   影响因子和分区

2567-3165

Anti-perovskites X(3)BA, as the electrically inverted derivatives of perovskites ABX(3), have attracted tremendous attention for their good performances in multiple disciplines, especially in energy storage batteries. The Li/Na-rich antiperovskite (LiRAP/NaRAP) solid-state electrolytes (SSEs) typically show high ionic conductivities and high chemical/electrochemical stability toward the Li-metal anode, illustrating their great potential for applications in the Li-metal batteries (LMBs) using nonaqueous liquid electrolyte or all-solid-state electrolyte. The antiperovskites have been studied as artificial solid electrolyte interphase for Li-metal anode protection, film SSEs for thin-film batteries, and low melting temperature solid electrolyte enabling melt-infiltration for the manufacture of all-solid-state lithium batteries. Transition metal-doped LiRAPs as cathodes have demonstrated a high discharge specific capacity and good rate capability in the Li-ion batteries (LIBs). Additionally, the underlying scientific principles in antiperovskites with flexible structural features have also been extensively studied. In this review, we comprehensively summarize the development, structural design, ionic conductivity and ion transportation mechanism, chemical/electrochemical stability, and applications of some antiperovskite materials in energy storage batteries. The perspective for enhancing the performance of the antiperovskites is also provided as a guide for future development and applications in energy storage.

antiperovskite chemical and electrochemical stability energy storage solid-state electrolyte

SCI

英语

第一 ; 通讯

National Natural Science Foundation of China[51732005] ; Guangdong Basic and Applied Basic Research Foundation[2021A1515011784] ; Shenzhen Science and Technology Program[KQTD20200820113047086]

Materials Science

Materials Science, Multidisciplinary

WOS:000699967200001

WILEY

Web of Science

1.Southern Univ Sci & Technol, Dept Phys & Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China
2.Southern Univ Sci & Technol, Key Lab Energy Convers & Storage Technol, Minist Educ, Shenzhen, Peoples R China
3.Chinese Acad Sci, Beijing Key Lab New Energy Mat & Devices, Inst Phys, Key Lab Renewable Energy, Beijing 100190, Peoples R China
4.Univ Chinese Acad Sci, Coll Mat Sci & Opto Elect Technol, Sch Phys Sci, Beijing, Peoples R China

Deng, Zhi,Ni, Dixing,Chen, Diancheng,et al. Anti-perovskite materials for energy storage batteries[J]. INFOMAT,2021.

Deng, Zhi.,Ni, Dixing.,Chen, Diancheng.,Bian, Ying.,Li, Shuai.,...&Zhao, Yusheng.(2021).Anti-perovskite materials for energy storage batteries.INFOMAT.

Deng, Zhi,et al."Anti-perovskite materials for energy storage batteries".INFOMAT (2021).