南方科技大学知识苑(SUSTech KC): Interfacing with Fe-N-C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles

题名	Interfacing with Fe-N-C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles
作者	Zhong, Shan 1,2,3; Yang, Xinchun 1; Chen, Liyu 4,5; Tsumori, Nobuko 6; Taguchi, Noboru 1; Xu, Qiang1,2,4,5,7
通讯作者	Xu, Qiang
发表日期	2021-10-06
DOI	10.1021/acsami.1c14009
发表期刊	ACS Applied Materials & Interfaces 影响因子和分区
ISSN	1944-8244
EISSN	1944-8252
卷号	13 期号:39页码:46749-46755
摘要	Hierarchical micro-/mesoporous carbons with abundant Fe-N-C sites were prepared through one-step carbonization of a metal-organic framework (MOF) with sodium iron ethylenediaminetetraacetic acid [NaFe(III)EDTA], which can facilitate the nucleation and growth of ultrafine (similar to 1.4 nm) and highly dispersed palladium nanoparticles (Pd NPs). Interfacing Pd NPs with Fe-N-C sites has been demonstrated for the first time to boost the heterogeneous catalysis of hydrogen production from formic acid, affording an ultrahigh turnover frequency (TOF) value of 7361 h(-1) at 323 K. The robust synergistic interactions between Pd NPs and Fe-N-C sites together with the small size effects of Pd NPs are responsible for the enhanced catalytic activity.
关键词	Palladium Nanoparticles Fe-n-c Sites Hydrogen Generation Formic Acid Catalysis
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	通讯
WOS研究方向	Science & Technology - Other Topics ; Materials Science
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000706187100052
出版者	AMER CHEMICAL SOC
EI入藏号	20214211041370
EI主题词	Carbonization ; Catalysis ; Catalyst activity ; Ethylenediaminetetraacetic acid ; Hydrogen production ; Iron compounds ; Metal nanoparticles ; Organometallics ; Palladium
EI分类号	Gas Fuels:522 ; Precious Metals:547.1 ; Nanotechnology:761 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1
来源库	Web of Science
引用统计	被引频次[WOS]：27
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/254171
专题	工学院_材料科学与工程系
作者单位	1.Natl Inst Adv Ind Sci & Technol, Res Inst Electrochem Energy, Ikeda, Osaka 5638577, Japan 2.Kobe Univ, Grad Sch Engn, Kobe, Hyogo 6578501, Japan 3.Jiangsu Univ, Sch Energy & Power Engn, Zhenjiang 212013, Jiangsu, Peoples R China 4.Kyoto Univ, AIST Kyoto Univ Chem Energy Mat Open Innovat Lab, Natl Inst Adv Ind Sci & Technol AIST, Kyoto 6068501, Japan 5.Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Kyoto 6068501, Japan 6.Toyama Natl Coll Technol, Dept Appl Chem & Chem Engn, Toyama 9398630, Japan 7.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Guangdong, Peoples R China
通讯作者单位	材料科学与工程系
推荐引用方式 GB/T 7714	Zhong, Shan,Yang, Xinchun,Chen, Liyu,et al. Interfacing with Fe-N-C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles[J]. ACS Applied Materials & Interfaces,2021,13(39):46749-46755.
APA	Zhong, Shan,Yang, Xinchun,Chen, Liyu,Tsumori, Nobuko,Taguchi, Noboru,&Xu, Qiang.(2021).Interfacing with Fe-N-C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles.ACS Applied Materials & Interfaces,13(39),46749-46755.
MLA	Zhong, Shan,et al."Interfacing with Fe-N-C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles".ACS Applied Materials & Interfaces 13.39(2021):46749-46755.

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