题名 | Highly phosphorescent organopalladium(ii) complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions |
作者 | |
通讯作者 | Lu, Wei |
发表日期 | 2019-07-28
|
DOI | |
发表期刊 | |
ISSN | 1477-9226
|
EISSN | 1477-9234
|
卷号 | 48期号:28页码:10417-10421 |
摘要 | Dinuclear pincer-type cyclometalated Pd(ii) complexes with foldable diacetylide ligands show crystallographically determined intramolecular PdMIDLINE HORIZONTAL ELLIPSISPd contacts of 3.203-3.380 angstrom. In deoxygenated fluid solutions, these Pd(ii) complexes are highly phosphorescent in the red region with emission quantum yields up to 48%, which has been ascribed to metal-metal-to-ligand charge-transfer (MMLCT) excited states in nature. |
相关链接 | [来源记录] |
收录类别 | |
语种 | 英语
|
学校署名 | 第一
; 通讯
|
资助项目 | Science and Technology Innovation Commission of Shenzhen Municipality[JCYJ 20160301114634613]
; Science and Technology Innovation Commission of Shenzhen Municipality[JCYJ20170817104715174]
|
WOS研究方向 | Chemistry
|
WOS类目 | Chemistry, Inorganic & Nuclear
|
WOS记录号 | WOS:000476573300006
|
出版者 | |
EI入藏号 | 20192907209785
|
EI主题词 | Charge transfer
; Excited states
; Ligands
; Metals
; Phosphorescence
; Quantum theory
|
EI分类号 | Light/Optics:741.1
; Physical Chemistry:801.4
; Chemical Reactions:802.2
; Quantum Theory; Quantum Mechanics:931.4
|
ESI学科分类 | CHEMISTRY
|
来源库 | Web of Science
|
引用统计 |
被引频次[WOS]:20
|
成果类型 | 期刊论文 |
条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/25463 |
专题 | 理学院_化学系 |
作者单位 | Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China |
第一作者单位 | 化学系 |
通讯作者单位 | 化学系 |
第一作者的第一单位 | 化学系 |
推荐引用方式 GB/T 7714 |
Lin, Jinqiang,Zou, Chao,Zhang, Xiaobao,et al. Highly phosphorescent organopalladium(ii) complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions[J]. DALTON TRANSACTIONS,2019,48(28):10417-10421.
|
APA |
Lin, Jinqiang.,Zou, Chao.,Zhang, Xiaobao.,Gao, Qin.,Suo, Sa.,...&Lu, Wei.(2019).Highly phosphorescent organopalladium(ii) complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions.DALTON TRANSACTIONS,48(28),10417-10421.
|
MLA |
Lin, Jinqiang,et al."Highly phosphorescent organopalladium(ii) complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions".DALTON TRANSACTIONS 48.28(2019):10417-10421.
|
条目包含的文件 | 条目无相关文件。 |
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