| 题名 | La3B14-: an inverse triple-decker lanthanide boron cluster |
| 作者 | |
| 通讯作者 | Li, Jun; Wang, Lai-Sheng |
| 发表日期 | 2019-07-11
|
| DOI | |
| 发表期刊 | |
| ISSN | 1359-7345
|
| EISSN | 1364-548X
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| 卷号 | 55期号:54页码:7864-7867 |
| 摘要 | We report the observation of the first inverse triple-decker complex in a tri-lanthanide-doped boron cluster. Photoelectron spectroscopy of La3B14- reveals well-resolved photodetachment transitions. Quantum chemical studies show that the most stable structure of the La3B14- cluster exhibits a tilted La-B-8-La-B-8-La inverse triple-decker structure with two conjoined B-8 rings sharing a pair of B atoms due to strong inter-layer B-B bonding. The tilted structure enhances both B-B and B-La bonding, resulting in a highly stable inverse triple-decker structure. Theoretical calculations further show that multi-decker conjoined structures are viable as a new class of 1D lanthanide boron nanostructures. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI期刊
|
| 学校署名 | 通讯
|
| 资助项目 | National Natural Science Foundation of China[21590792]
; National Natural Science Foundation of China[91426302]
; National Natural Science Foundation of China[21433005]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
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| WOS记录号 | WOS:000474265200030
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| 出版者 | |
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
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| 引用统计 |
被引频次[WOS]：41
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/25521 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Brown Univ, Dept Chem, Providence, RI 02912 USA 2.Tsinghua Univ, Minist Educ, Dept Chem, Beijing 100084, Peoples R China 3.Tsinghua Univ, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China 4.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China |
| 通讯作者单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Chen, Teng-Teng,Li, Wan-Lu,Chen, Wei-Jia,et al. La3B14-: an inverse triple-decker lanthanide boron cluster[J]. CHEMICAL COMMUNICATIONS,2019,55(54):7864-7867.
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| APA |
Chen, Teng-Teng,Li, Wan-Lu,Chen, Wei-Jia,Li, Jun,&Wang, Lai-Sheng.(2019).La3B14-: an inverse triple-decker lanthanide boron cluster.CHEMICAL COMMUNICATIONS,55(54),7864-7867.
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| MLA |
Chen, Teng-Teng,et al."La3B14-: an inverse triple-decker lanthanide boron cluster".CHEMICAL COMMUNICATIONS 55.54(2019):7864-7867.
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| 条目包含的文件 | 条目无相关文件。 | |||||
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