| 题名 | Monovalent lanthanide(I) in borozene complexes |
| 作者 | |
| 通讯作者 | Li，Jun |
| 发表日期 | 2021-12-01
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| DOI | |
| 发表期刊 | |
| EISSN | 2041-1723
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| 卷号 | 12期号:1 |
| 摘要 | Lanthanide (Ln) elements are generally found in the oxidation state +II or +III, and a few examples of +IV and +V compounds have also been reported. In contrast, monovalent Ln(+I) complexes remain scarce. Here we combine photoelectron spectroscopy and theoretical calculations to study Ln-doped octa-boron clusters (LnB, Ln = La, Pr, Tb, Tm, Yb) with the rare +I oxidation state. The global minimum of the LnB species changes from C to C symmetry accompanied by an oxidation-state change from +III to +I from the early to late lanthanides. All the C-LnB clusters can be viewed as a monovalent Ln(I) coordinated by a η-B doubly aromatic ligand. The B, B, and B series of aromatic boron clusters are analogous to the classical aromatic hydrocarbon molecules, CH, CH, and CH, respectively, with similar trends of size and charge state and they are named collectively as “borozenes”. Lanthanides with variable oxidation states and magnetic properties may be formed with different borozenes. |
| 相关链接 | [Scopus记录] |
| 收录类别 | |
| 语种 | 英语
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| 重要成果 | NI论文
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| 学校署名 | 通讯
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| 资助项目 | National Science Foundation[CHE-2053541]
; National Natural Science Foundation of China[22033005]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
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| WOS研究方向 | Science & Technology - Other Topics
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| WOS类目 | Multidisciplinary Sciences
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| WOS记录号 | WOS:000716589100029
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| 出版者 | |
| Scopus记录号 | 2-s2.0-85118648908
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| 来源库 | Scopus
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| 引用统计 |
被引频次[WOS]：28
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| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/255363 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education,Tsinghua University,Beijing,100084,China 2.Department of Chemistry,Brown University,Providence,02912,United States 3.Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China |
| 通讯作者单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Li，Wan Lu,Chen，Teng Teng,Chen，Wei Jia,et al. Monovalent lanthanide(I) in borozene complexes[J]. Nature Communications,2021,12(1).
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| APA |
Li，Wan Lu,Chen，Teng Teng,Chen，Wei Jia,Li，Jun,&Wang，Lai Sheng.(2021).Monovalent lanthanide(I) in borozene complexes.Nature Communications,12(1).
|
| MLA |
Li，Wan Lu,et al."Monovalent lanthanide(I) in borozene complexes".Nature Communications 12.1(2021).
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| 条目包含的文件 | 条目无相关文件。 | |||||
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