南方科技大学知识苑(SUSTech KC): Metallacycle Expansion and Annulation: Access to Tetrazolo-Fused Osmacycles by Reaction of Cyclic Osmium Carbyne with Sodium Azide

题名	Metallacycle Expansion and Annulation: Access to Tetrazolo-Fused Osmacycles by Reaction of Cyclic Osmium Carbyne with Sodium Azide
作者	Wang，Hongjian 1; Lin，Yu Mei 1; Chen，Siyuan 1; Ruan，Yonghong 1; Xia，Haiping1,2
通讯作者	Xia，Haiping
发表日期	2021
DOI	10.1002/cjoc.202100589
发表期刊	CHINESE JOURNAL OF CHEMISTRY 影响因子和分区
ISSN	1001-604X
EISSN	1614-7065
摘要	The reaction of a cyclic osmacarbyne complex with sodium azide led to the formation of a ring expansion-annulation product, a unique tetrazole annulated polycyclic metallacycle. The reaction proceeds by insertion of a nitrogen atom into the metal carbon triple bond and the second azide participating in the [2+3] cycloaddition. The successful isolation and characterization of metalla-azirine complex and metallapyridinium derivative strongly validated the mechanism for the formation of the title complex. The work demonstrates a new strategy to enrich the varieties of aza-metallacyclic species.
关键词	Annulation Aza-heterocycle Metallacycles Osmium carbyne Ring expansion
相关链接	[Scopus记录]
收录类别	SCI
语种	英语
学校署名	通讯
资助项目	National Natural Science Foundation of China[22071206,"U1705254",21931002] ; Natural Science Foundation of Fujian Province of China[2020J01025]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000714902500001
出版者	WILEY-V C H VERLAG GMBH
ESI学科分类	CHEMISTRY
Scopus记录号	2-s2.0-85118596443
来源库	Scopus
引用统计	被引频次[WOS]：14
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/255464
专题	理学院_化学系深圳格拉布斯研究院
作者单位	1.State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen,361005,China 2.Shenzhen Grubbs Institute,Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China
通讯作者单位	化学系; 深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Wang，Hongjian,Lin，Yu Mei,Chen，Siyuan,et al. Metallacycle Expansion and Annulation: Access to Tetrazolo-Fused Osmacycles by Reaction of Cyclic Osmium Carbyne with Sodium Azide[J]. CHINESE JOURNAL OF CHEMISTRY,2021.
APA	Wang，Hongjian,Lin，Yu Mei,Chen，Siyuan,Ruan，Yonghong,&Xia，Haiping.(2021).Metallacycle Expansion and Annulation: Access to Tetrazolo-Fused Osmacycles by Reaction of Cyclic Osmium Carbyne with Sodium Azide.CHINESE JOURNAL OF CHEMISTRY.
MLA	Wang，Hongjian,et al."Metallacycle Expansion and Annulation: Access to Tetrazolo-Fused Osmacycles by Reaction of Cyclic Osmium Carbyne with Sodium Azide".CHINESE JOURNAL OF CHEMISTRY (2021).