南方科技大学知识苑(SUSTech KC): A rhodium(III)-catalyzed tunable coupling reaction of indole derivatives with alkylidenecyclopropanes via C-H activation

题名	A rhodium(III)-catalyzed tunable coupling reaction of indole derivatives with alkylidenecyclopropanes via C-H activation
作者	Liu, Ruixing 1; Wei, Yin 1; Shi, Min1,2
通讯作者	Shi, Min
发表日期	2019-07-04
DOI	10.1039/c9cc03134k
发表期刊	CHEMICAL COMMUNICATIONS 影响因子和分区
ISSN	1359-7345
EISSN	1364-548X
卷号	55 期号:52页码:7558-7561
摘要	We herein report a rhodium(iii)-catalyzed cross coupling of indole derivatives with alkylidenecyclopropanes (ACPs) in the presence of KCl, affording the alkene products exclusively with E-selectivity via C-H bond activation. The beta-H elimination to afford the conjugated diene derivatives has been suppressed by the addition of KCl. A plausible reaction mechanism has been proposed along with derivatization of the obtained product to demonstrate the practical usefulness of this synthetic protocol.
相关链接	[来源记录]
收录类别	SCI ; IC ; CCR ; EI
语种	英语
重要成果	NI期刊
学校署名	通讯
资助项目	National Natural Science Foundation of China[20472096] ; National Natural Science Foundation of China[21372241] ; National Natural Science Foundation of China[21572052] ; National Natural Science Foundation of China[20672127] ; National Natural Science Foundation of China[21421091] ; National Natural Science Foundation of China[21372250] ; National Natural Science Foundation of China[21121062] ; National Natural Science Foundation of China[21302203] ; National Natural Science Foundation of China[21772226] ; National Natural Science Foundation of China[20732008] ; National Natural Science Foundation of China[21772037] ; National Natural Science Foundation of China[21861132014]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000472790500028
出版者	ROYAL SOC CHEMISTRY
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：17
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/25546
专题	深圳格拉布斯研究院
作者单位	1.Chinese Acad Sci, Univ Chinese Acad Sci, State Key Lab Organometall Chem, Ctr Excellence Mol Synth,Shanghai Inst Organ Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518000, Guangdong, Peoples R China
通讯作者单位	深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Liu, Ruixing,Wei, Yin,Shi, Min. A rhodium(III)-catalyzed tunable coupling reaction of indole derivatives with alkylidenecyclopropanes via C-H activation[J]. CHEMICAL COMMUNICATIONS,2019,55(52):7558-7561.
APA	Liu, Ruixing,Wei, Yin,&Shi, Min.(2019).A rhodium(III)-catalyzed tunable coupling reaction of indole derivatives with alkylidenecyclopropanes via C-H activation.CHEMICAL COMMUNICATIONS,55(52),7558-7561.
MLA	Liu, Ruixing,et al."A rhodium(III)-catalyzed tunable coupling reaction of indole derivatives with alkylidenecyclopropanes via C-H activation".CHEMICAL COMMUNICATIONS 55.52(2019):7558-7561.