Hierarchical Chiral Supramolecular Nanoarchitectonics with Molecular Detection: Helical Structure Controls upon Self-Assembly and Coassembly

Li，Heng1,2; Han，Liang1; Li，Qing3; Lai，Hanjian1; Fernández-Trillo，Paco2,4; Tian，Leilei3; He，Feng1,5

2021

10.1002/marc.202100690

MACROMOLECULAR RAPID COMMUNICATIONS   影响因子和分区

1022-1336

1521-3927

The morphological transformation from microspheres to helical supramolecular nanofibers with controllable handedness is achieved by the introduction of molecular chirality based on amino acid derivatives (TDAP), and the chirality of the supramolecular architectures that are achieved is nullified through the coassembly of the equivalent TDAP enantiomers. The molecular detection of achiral melamine based on the R-TDAP-COOH supramolecular system is achieved by the appearance of helicity and inversion.

chiral supramolecular structures functionalized supramolecules hierarchical self-assembly molecular detection supramolecular self-assembly

SCI ; EI

英语

第一 ; 通讯

National Natural Science Foundation of China[21975115,21733005] ; Shenzhen Fundamental Research Programs["JCYJ20190809161413310","JCYJ20180302180238419"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Guangdong Basic and Applied Basic Research Foundation[2020A1515110845] ; Guangdong Innovative and Entrepreneurial Research Team Program[2016ZT06G587] ; Shenzhen Sci-Tech Fund[KYTDPT20181011104007]

Polymer Science

Polymer Science

WOS:000719676200001

WILEY-V C H VERLAG GMBH

20214711185733

Chirality ; Self assembly

Physical Chemistry:801.4 ; Atomic and Molecular Physics:931.3 ; Materials Science:951

CHEMISTRY

2-s2.0-85119179860

Scopus

1.Shenzhen Grubbs Institute and Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China
2.School of Chemistry,University of Birmingham,Birmingham,B15 2TT,United Kingdom
3.Department of Materials Science and Engineering,Southern University of Science and Technology,Shenzhen,518055,China
4.Departamento de Química,Facultade de Ciencias and Centro de Investigacións Científicas Avanzadas (CICA),Universidade da Coruña A Coruña,15071,Spain
5.Guangdong Provincial Key Laboratory of Catalysis,Southern University of Science and Technology,Shenzhen,518055,China

Li，Heng,Han，Liang,Li，Qing,et al. Hierarchical Chiral Supramolecular Nanoarchitectonics with Molecular Detection: Helical Structure Controls upon Self-Assembly and Coassembly[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2021,43.

Li，Heng.,Han，Liang.,Li，Qing.,Lai，Hanjian.,Fernández-Trillo，Paco.,...&He，Feng.(2021).Hierarchical Chiral Supramolecular Nanoarchitectonics with Molecular Detection: Helical Structure Controls upon Self-Assembly and Coassembly.MACROMOLECULAR RAPID COMMUNICATIONS,43.

Li，Heng,et al."Hierarchical Chiral Supramolecular Nanoarchitectonics with Molecular Detection: Helical Structure Controls upon Self-Assembly and Coassembly".MACROMOLECULAR RAPID COMMUNICATIONS 43(2021).