南方科技大学知识苑(SUSTech KC): Symbiotic crystal-glass alloys via dynamic chemical partitioning

题名	Symbiotic crystal-glass alloys via dynamic chemical partitioning
作者	Wu，Ge 1; Liu，Chang 1; Brognara，Andrea 1; Ghidelli，Matteo 1,2; Bao，Yan 3; Liu，Sida 3; Wu，Xiaoxiang 1,4; Xia，Wenzhen 1,5; Zhao，Huan 1; Rao，Jing 1; Ponge，Dirk 1; Devulapalli，Vivek 1; Lu，Wenjun1,6 ; Dehm，Gerhard 1; Raabe，Dierk 1; Li，Zhiming 7,8; Wu，Ge 9; Liu，Chang 9; Brognara，Andrea 9; Ghidelli，Matteo 9,10; Bao，Yan 11; Liu，Sida 11; Wu，Xiaoxiang 9,12; Xia，Wenzhen 9,13; Zhao，Huan 9; Rao，Jing 9; Ponge，Dirk 9; Devulapalli，Vivek 9; Lu，Wenjun9,14 ; Dehm，Gerhard 9; Raabe，Dierk 9; Li，Zhiming 15,16
通讯作者	Ghidelli，Matteo; Lu，Wenjun; Raabe，Dierk; Li，Zhiming; Ghidelli，Matteo; Lu，Wenjun; Raabe，Dierk; Li，Zhiming
发表日期	2021
DOI	10.1016/j.mattod.2021.10.025
发表期刊	Materials Today 影响因子和分区
ISSN	1369-7021
EISSN	1873-4103
卷号	51页码:6-14
摘要	The design of high performance structural materials is always pursuing combinations of excellent yet often mutually exclusive properties such as mechanical strength, ductility and thermal stability. Although crystal-glass composite alloys provide better ductility compared to fully amorphous alloys, their thermal stability is poor, due to heterogeneous nucleation at the crystal-glass interface. Here we present a new strategy to develop thermally stable, ultrastrong and deformable crystal-glass nanocomposites through a thermodynamically guided alloy design approach, which mimics the mutual stabilization principle known from symbiotic ecosystems. We realized this in form of a model Cr-Co-Ni (crystalline)/Ti-Zr-Nb-Hf-Cr-Co-Ni (amorphous) laminate composite alloy. The symbiotic alloy has an ultrahigh compressive yield strength of 3.6 GPa and large homogeneous deformation of ∼15% strain at ambient temperature, values which surpass those of conventional metallic glasses and nanolaminate alloys. Furthermore, the alloy exhibits ∼200 K higher crystallization temperature (T > 973 K) compared to that of the original TiZrNbHf-based amorphous phase. The elemental partitioning among adjacent amorphous and crystalline phases leads to their mutual thermodynamic and mechanical stabilization, opening up a new symbiotic approach for stable, strong and ductile materials.
关键词	Crystal-glass Composite Alloys Dynamic Chemical Partitioning Nanostructure Strong And Ductile Thermal Stability
相关链接	[Scopus记录]
收录类别	EI
语种	英语
学校署名	通讯
EI入藏号	20214611179231
EI主题词	Amorphous alloys ; Chemical stability ; Chromium alloys ; Cobalt alloys ; Crystallization ; Deformation ; Ductility ; Glass ; Iron alloys ; Laminated composites ; Metallic glass ; Niobium alloys ; Nucleation ; Stabilization ; Thermodynamic stability ; Zircaloy
EI分类号	Metallurgy and Metallography:531 ; Chromium and Alloys:543.1 ; Iron Alloys:545.2 ; Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Thermodynamics:641.1 ; Chemistry:801 ; Chemical Operations:802.3 ; Glass:812.3 ; Crystal Growth:933.1.2 ; Materials Science:951
Scopus记录号	2-s2.0-85119069947
来源库	Scopus
引用统计	被引频次[WOS]：45
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/256363
专题	工学院_机械与能源工程系
作者单位	1.Max-Planck-Institut für Eisenforschung,Düsseldorf,Max-Planck-Straße 1,40237,Germany 2.Laboratoire des Sciences des Procédés et des Matériaux (LSPM),CNRS,Université Sorbonne Paris Nord,Villetaneuse,93430,France 3.Department of Mechanical Engineering,City University of Hong Kong,Hong Kong 4.Shagang School of Iron and Steel,Soochow University,Suzhou,215137,China 5.School of Metallurgical Engineering,Anhui University of Technology,Maanshan,243000,China 6.Department of Mechanical and Energy Engineering,Southern University of Science and Technology,Shenzhen,518055,China 7.School of Materials Science and Engineering,Central South University,Changsha,410083,China 8.Key Laboratory of Nonferrous Metal Materials Science and Engineering,Ministry of Education,Central South University,Changsha,410083,China 9.Max-Planck-Institut für Eisenforschung,Düsseldorf,Max-Planck-Straße 1,40237,Germany 10.Laboratoire des Sciences des Procédés et des Matériaux (LSPM),CNRS,Université Sorbonne Paris Nord,Villetaneuse,93430,France 11.Department of Mechanical Engineering,City University of Hong Kong,Hong Kong 12.Shagang School of Iron and Steel,Soochow University,Suzhou,215137,China 13.School of Metallurgical Engineering,Anhui University of Technology,Maanshan,243000,China 14.Department of Mechanical and Energy Engineering,Southern University of Science and Technology,Shenzhen,518055,China 15.School of Materials Science and Engineering,Central South University,Changsha,410083,China 16.Key Laboratory of Nonferrous Metal Materials Science and Engineering,Ministry of Education,Central South University,Changsha,410083,China
通讯作者单位	机械与能源工程系
推荐引用方式 GB/T 7714	Wu，Ge,Liu，Chang,Brognara，Andrea,et al. Symbiotic crystal-glass alloys via dynamic chemical partitioning[J]. Materials Today,2021,51:6-14.
APA	Wu，Ge.,Liu，Chang.,Brognara，Andrea.,Ghidelli，Matteo.,Bao，Yan.,...&Li，Zhiming.(2021).Symbiotic crystal-glass alloys via dynamic chemical partitioning.Materials Today,51,6-14.
MLA	Wu，Ge,et al."Symbiotic crystal-glass alloys via dynamic chemical partitioning".Materials Today 51(2021):6-14.