南方科技大学知识苑(SUSTech KC): Asymmetric hydrogenation of 1,4-diketones: facile synthesis of enantiopure 1,4-diarylbutane-1,4-diols

题名	Asymmetric hydrogenation of 1,4-diketones: facile synthesis of enantiopure 1,4-diarylbutane-1,4-diols
作者	Song, Jingyuan1,2 ; Shao, Pan-Lin2,3 ; Wang, Jiang2 ; Huang, Fanping2 ; Zhang, Xumu2,4
通讯作者	Shao, Pan-Lin; Zhang, Xumu
发表日期	2021-11-01
DOI	10.1039/d1cc05359k
发表期刊	CHEMICAL COMMUNICATIONS 影响因子和分区
ISSN	1359-7345
EISSN	1364-548X
卷号	58 期号:2页码:262-265
摘要	Owing to the biological significance and great synthetic value of 1,4-diarylbutane-1,4-diols and their derivatives, increasingly considerable attention has been paid to developing effective synthetic methods for chiral 1,4-diarylbutane-1,4-diols. We herein report an efficient asymmetric hydrogenation of 1,4-diaryldiketones catalyzed by a chiral iridium complex bearing f-amphox as ligand, furnishing a series of 1,4-diarylbutane-1,4-diols in excellent yields (up to >99%) with exceptional enantioselectivities (up to >99.9% ee) and diastereoselectivities (up to >100 : 1 dr).
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
重要成果	NI论文
学校署名	通讯
资助项目	Science, Technology and Innovation Commission of Shenzhen["JCYJ20190809160211372","JCYJ20210324104007020"] ; National Natural Science Foundation of China[21991113] ; Shenzhen Clean Energy Research Institute[CERI-KY-2019-003] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000728641700001
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20220111424684
EI主题词	Iridium compounds
EI分类号	Chemical Reactions:802.2
ESI学科分类	CHEMISTRY
Scopus记录号	2-s2.0-85122063773
来源库	Web of Science
引用统计	被引频次[WOS]：6
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/258541
专题	理学院_化学系创新创业学院
作者单位	1.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, 1088 Xueyuan Rd, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Coll Innovat & Entrepreneurship, 1088 Xueyuan Rd, Shenzhen 518055, Peoples R China 4.Southern Univ Sci & Technol, Medi X Pingshan, Shenzhen 518118, Guangdong, Peoples R China
第一作者单位	化学系
通讯作者单位	化学系; 创新创业学院; 南方科技大学
推荐引用方式 GB/T 7714	Song, Jingyuan,Shao, Pan-Lin,Wang, Jiang,et al. Asymmetric hydrogenation of 1,4-diketones: facile synthesis of enantiopure 1,4-diarylbutane-1,4-diols[J]. CHEMICAL COMMUNICATIONS,2021,58(2):262-265.
APA	Song, Jingyuan,Shao, Pan-Lin,Wang, Jiang,Huang, Fanping,&Zhang, Xumu.(2021).Asymmetric hydrogenation of 1,4-diketones: facile synthesis of enantiopure 1,4-diarylbutane-1,4-diols.CHEMICAL COMMUNICATIONS,58(2),262-265.
MLA	Song, Jingyuan,et al."Asymmetric hydrogenation of 1,4-diketones: facile synthesis of enantiopure 1,4-diarylbutane-1,4-diols".CHEMICAL COMMUNICATIONS 58.2(2021):262-265.