| 题名 | Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations |
| 作者 | |
| 通讯作者 | Yang, Yi; Chung, Lungwa; Vicic, David A. |
| 发表日期 | 2019-05-28
|
| DOI | |
| 发表期刊 | |
| ISSN | 2041-6520
|
| EISSN | 2041-6539
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| 卷号 | 10期号:20页码:5275-5282 |
| 摘要 | We report herein the exploitment of the partially fluorinated trifluoroethyl as precatalyst ligands in nickelcatalyzed Suzuki-type alkylation and fluoroalkylation coupling reactions. Compared with the [LnNiII(aryl)(X)] precatalysts, the unique characters of bis-trifluoroethyl ligands imparted precatalyst [(bipy) Ni(CH2CF3) (2)] with bench-top stability, good solubilities in organic media and interesting catalytic activities. Preliminary mechanistic studies reveal that an eliminative extrusion of a vinylidene difluoride (VDF, CH2] CF2) mask from [(bipy) Ni(CH2CF3) (2)] is a critical step for the initiation of a catalytic reaction. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI期刊
|
| 学校署名 | 通讯
|
| 资助项目 | Office of Basic Energy Sciences of the U.S. Department of Energy[DE-SC0009363]
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| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
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| WOS记录号 | WOS:000468791800007
|
| 出版者 | |
| EI入藏号 | 20192206979026
|
| EI主题词 | Alkylation
; Catalysis
; Catalyst Activity
; Nickel
; Nickel Compounds
|
| EI分类号 | Nickel:548.1
; Physical Chemistry:801.4
; Chemical Reactions:802.2
; Chemical Agents And Basic Industrial Chemicals:803
; Chemical Products Generally:804
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：13
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/25855 |
| 专题 | 深圳格拉布斯研究院 理学院_化学系 |
| 作者单位 | 1.Sichuan Univ Sci & Engn, Sch Chem & Environm Engn, Higher Educ Inst Sichuan, Key Lab Green Catalysis, 180 Xueyuan St, Zigong 643000, Sichuan, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 4.Lehigh Univ, Dept Chem, 6 E Packer Ave, Bethlehem, PA 18015 USA |
| 通讯作者单位 | 深圳格拉布斯研究院; 化学系 |
| 推荐引用方式 GB/T 7714 |
Yang, Yi,Zhou, Qinghai,Cai, Junjie,et al. Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations[J]. Chemical Science,2019,10(20):5275-5282.
|
| APA |
Yang, Yi.,Zhou, Qinghai.,Cai, Junjie.,Xue, Teng.,Liu, Yingle.,...&Vicic, David A..(2019).Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations.Chemical Science,10(20),5275-5282.
|
| MLA |
Yang, Yi,et al."Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations".Chemical Science 10.20(2019):5275-5282.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| Yang-2019-Exploiting（1261KB） | -- | -- | 开放获取 | -- | 浏览 | |
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