Formal [2+2+2] Cycloaddition Reaction of a Metal-Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex

Lin, Jianfeng1,2; Ding, Linting1,2; Zhuo, Qingde1,2; Zhang, Hong1,2; Xia, Haiping1,2,3

2019-05-13

10.1021/acs.organomet.9b00213

ORGANOMETALLICS   影响因子和分区

0276-7333

1520-6041

Although alkynes have been extensively exploited in [2 + 2 + 2] cycloadditions with nitriles to form N-heterocyclic aromatics, the "alkyne-like" metal carbon triple bond has never been used in [2 + 2 + 2] cycloadditions with nitriles. We demonstrate the synthesis of the first metallapyrazine through [2 + 2 + 2] cycloaddition reactions of a metal carbyne complex with nitriles. Experimental observations and density functional theory calculations are evidence for the aromatic character of the metallapentalenopyrazine.

SCI ; EI

英语

通讯

National Natural Science Foundation of China[U1705254] ; National Natural Science Foundation of China[21572185] ; National Natural Science Foundation of China[21561162001]

Chemistry

Chemistry, Inorganic & Nuclear ; Chemistry, Organic

WOS:000468120200046

AMER CHEMICAL SOC

20192006936152

Cyanides ; Density functional theory ; Hydrocarbons ; Metals

Chemical Reactions:802.2 ; Organic Compounds:804.1 ; Inorganic Compounds:804.2 ; Probability Theory:922.1

CHEMISTRY

Web of Science

1.Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
2.Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat iChEM, Xiamen 361005, Peoples R China
3.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China

Lin, Jianfeng,Ding, Linting,Zhuo, Qingde,et al. Formal [2+2+2] Cycloaddition Reaction of a Metal-Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex[J]. ORGANOMETALLICS,2019,38(9):2264-2271.

Lin, Jianfeng,Ding, Linting,Zhuo, Qingde,Zhang, Hong,&Xia, Haiping.(2019).Formal [2+2+2] Cycloaddition Reaction of a Metal-Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex.ORGANOMETALLICS,38(9),2264-2271.

Lin, Jianfeng,et al."Formal [2+2+2] Cycloaddition Reaction of a Metal-Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex".ORGANOMETALLICS 38.9(2019):2264-2271.