南方科技大学知识苑(SUSTech KC): Thiacalixarene-Supported Irregular Co-26 and Ni-28 High-Nuclearity Clusters with Pyridyl-Diphosphonates: Strategies to Create Active Metal Sites and Fabricate Multicomponent Materials

题名	Thiacalixarene-Supported Irregular Co-26 and Ni-28 High-Nuclearity Clusters with Pyridyl-Diphosphonates: Strategies to Create Active Metal Sites and Fabricate Multicomponent Materials
作者	Chen, Mengwei 1; Zhang, Min 1; Wang, Xin 1; Bi, Yanfeng 1; Chen, Baokuan 1; Zheng, Zhiping1,2,3
通讯作者	Bi, Yanfeng; Zheng, Zhiping
发表日期	2019-05-06
DOI	10.1021/acs.inorgchem.9b00495
发表期刊	INORGANIC CHEMISTRY 影响因子和分区
ISSN	0020-1669
EISSN	1520-510X
卷号	58 期号:9页码:6276-6282
摘要	Two new irregularity high-nuclearity clusters [Co-26(TC4A)(6)(HL)(4)Cl-4(HCOO)(4)(CH3O)(2)(OH)(2) (DMF)(10)(H2O)(5)] (+ solvent) (Co-26) and [Ni-28(TC4A)(6)(HL)(6)(PO4)(2)(mu(3)-O)(2)Cl-2(CH3OH)(14)(H2O)(2) (DMF)(8)] [(CH3NH2CH3)(4)] (+ solvent) (Ni-28) have been solvothermally synthesized by p-tert-butylthiacalix[4]arene (H(4)TC4A), transition metals (CoCl2 center dot 6H(2)O/NiCl2-6H(2)O), and 1-hydroxy-2-(3-pyridinyl)ethylidene-1,1-diphosphonic acid (H5L). The clusters were structurally characterized by single crystal X-ray diffraction, PXRD, TGA, and FT-IR spectrum and Raman spectrum. Co-26 features a rodlike Co-26 core constructed by six Co-4-TC4A secondary building units (SBUs) and four HL4- with two extra cobalt ions. Ni-28 cluster represents a flowerlike Ni-28 core built from six Ni-4- TC4A SBUs, six HL4-, and four additional nickel ions. The multidentate risedronic acid displaying various new coordination mode bonds with SBUs to assemble two nanoclusters that enable high density possible coordinatively unsaturated metal sites (PCUMSs). Co-26 and Ni-28 clusters can be directly dispersed on carbon paper (CP) and showed extraordinary oxygen evolution reaction (OER) activity due to the larger exposed liable coordination active metal sites. The thermodecomposition of both nanoclusters at different temperatures afforded serial multicomponent complexes.
相关链接	[来源记录]
收录类别	SCI
语种	英语
重要成果	NI期刊
学校署名	通讯
资助项目	Shenzhen Nobel Prize Scientists Laboratory Project[C17213101]
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000467351100100
出版者	AMER CHEMICAL SOC
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：19
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/25933
专题	深圳格拉布斯研究院理学院_化学系
作者单位	1.Liaoning Shihua Univ, Coll Chem Chem Engn & Environm Engn, Fushun 113001, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518000, Guangdong, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518000, Guangdong, Peoples R China
通讯作者单位	深圳格拉布斯研究院; 化学系
推荐引用方式 GB/T 7714	Chen, Mengwei,Zhang, Min,Wang, Xin,et al. Thiacalixarene-Supported Irregular Co-26 and Ni-28 High-Nuclearity Clusters with Pyridyl-Diphosphonates: Strategies to Create Active Metal Sites and Fabricate Multicomponent Materials[J]. INORGANIC CHEMISTRY,2019,58(9):6276-6282.
APA	Chen, Mengwei,Zhang, Min,Wang, Xin,Bi, Yanfeng,Chen, Baokuan,&Zheng, Zhiping.(2019).Thiacalixarene-Supported Irregular Co-26 and Ni-28 High-Nuclearity Clusters with Pyridyl-Diphosphonates: Strategies to Create Active Metal Sites and Fabricate Multicomponent Materials.INORGANIC CHEMISTRY,58(9),6276-6282.
MLA	Chen, Mengwei,et al."Thiacalixarene-Supported Irregular Co-26 and Ni-28 High-Nuclearity Clusters with Pyridyl-Diphosphonates: Strategies to Create Active Metal Sites and Fabricate Multicomponent Materials".INORGANIC CHEMISTRY 58.9(2019):6276-6282.