Electronic Effects on Chiral NHC-Transition-Metal Catalysis

Yong, Xuefeng1,2; Thurston, Ryan1,3; Ho, Chun-Yu1

2019-05

10.1055/s-0037-1611751

SYNTHESIS-STUTTGART   影响因子和分区

0039-7881

1437-210X

Though the properties of N-heterocyclic carbenes (NHCs) are generally dominated by the very strong sigma donating character, electronic activation has emerged as an effective method to cooperate with typical carbon-framework steric optimization for highly enantioselective chiral NHC-transition-metal catalysis in recent years. NHC electronic changes associated with structural variations are now better understood by quantitative analysis using various methods. Here we highlighted and correlated some interesting chiral induction improvement methods, which were brought by electronic and steric cooperation on chiral NHC-transition-metal catalysis.

electronic effect chiral N-heterocyclic carbenes transition-metal catalysis enantioselective synthesis

SCI ; EI

英语

第一 ; 通讯

Shenzhen Key Laboratory of Full Spectral Solar Electricity Generation (FSSEG)[ZDSYS201602261933302]

Chemistry

Chemistry, Organic

WOS:000467273700002

GEORG THIEME VERLAG KG

20191906896891

Catalysis ; Enantioselectivity ; Organic compounds ; Silicon compounds ; Synthesis (chemical)

Metallurgy and Metallography:531 ; Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Organic Compounds:804.1

CHEMISTRY

Web of Science

1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Peoples R China
2.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin, Heilongjiang, Peoples R China
3.Friedrich Alexander Univ Erlangen Nurnberg, Dept Chem & Pharm, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany

Yong, Xuefeng,Thurston, Ryan,Ho, Chun-Yu. Electronic Effects on Chiral NHC-Transition-Metal Catalysis[J]. SYNTHESIS-STUTTGART,2019,51(10):2058-2080.

Yong, Xuefeng,Thurston, Ryan,&Ho, Chun-Yu.(2019).Electronic Effects on Chiral NHC-Transition-Metal Catalysis.SYNTHESIS-STUTTGART,51(10),2058-2080.

Yong, Xuefeng,et al."Electronic Effects on Chiral NHC-Transition-Metal Catalysis".SYNTHESIS-STUTTGART 51.10(2019):2058-2080.