南方科技大学知识苑(SUSTech KC): Chlorothiomethylation of Alkynes with HCl and Dimethyl Sulfoxide: An Efficient Approach to (E)-alpha-chloro-beta-(methylthio)alkenes

题名	Chlorothiomethylation of Alkynes with HCl and Dimethyl Sulfoxide: An Efficient Approach to (E)-alpha-chloro-beta-(methylthio)alkenes
作者	Tong, Hanqing.1; Chen, Cui 1; Liu, Weibing.1; Pan, Yupeng.2 ; Duan, Linhai.1
通讯作者	Liu, Weibing.; Duan, Linhai.
发表日期	2019-04
DOI	10.1002/ajoc.201900108
发表期刊	Asian Journal of Organic Chemistry 影响因子和分区
ISSN	2193-5807
EISSN	2193-5815
卷号	8 期号:4页码:479-481
摘要	Synthesis of (E)-chlorovinyl methylsulfanes via chlorothiomethylation of alkynes with HCl and dimethyl sulfoxide (DMSO) under metal-free and oxidant-free conditions has been reported. This methodology is rare, in which chlorovinyl methylsulfanes are constructed using chlorosulfanes rather than the combination of HCl and DMSO to react with alkynes. This procedure introduces a new application of DMSO, which is employed as a source of the SMe group to directly insert into the carbon-carbon triple bond of alkynes. Additionally, the reaction shows a broad substrate scope, good functional group compatibility, and excellent regioselectivity.
关键词	chlorothiomethylation metal-free alkynes DMSO HCl
相关链接	[来源记录]
收录类别	SCI ; IC
语种	英语
学校署名	其他
资助项目	Guangdong Natural Science Foundation[907017]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000466161500007
出版者	WILEY-V C H VERLAG GMBH
来源库	Web of Science
引用统计	被引频次[WOS]：16
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/26114
专题	深圳格拉布斯研究院
作者单位	1.Guangdong Univ Petrochem Technol, Coll Chem, 2 Guandu Rd, Maoming 525000, Peoples R China 2.Southern Univ Sci & Technol SUSTech, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Tong, Hanqing.,Chen, Cui,Liu, Weibing.,et al. Chlorothiomethylation of Alkynes with HCl and Dimethyl Sulfoxide: An Efficient Approach to (E)-alpha-chloro-beta-(methylthio)alkenes[J]. Asian Journal of Organic Chemistry,2019,8(4):479-481.
APA	Tong, Hanqing.,Chen, Cui,Liu, Weibing.,Pan, Yupeng.,&Duan, Linhai..(2019).Chlorothiomethylation of Alkynes with HCl and Dimethyl Sulfoxide: An Efficient Approach to (E)-alpha-chloro-beta-(methylthio)alkenes.Asian Journal of Organic Chemistry,8(4),479-481.
MLA	Tong, Hanqing.,et al."Chlorothiomethylation of Alkynes with HCl and Dimethyl Sulfoxide: An Efficient Approach to (E)-alpha-chloro-beta-(methylthio)alkenes".Asian Journal of Organic Chemistry 8.4(2019):479-481.