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题名

Infrared evidence for pressure-induced phase transition of alpha-Si3N4

作者
通讯作者Liu, Ke
发表日期
2019-03-20
DOI
发表期刊
ISSN
0217-9792
EISSN
1793-6578
卷号33期号:7
摘要
X-ray diffraction (XRD) method and structural refinement were used to characterize the sample of alpha-Si3N4. Rietveld analyses of XRD data confirmed that the sample belongs to hexagonal crystal (space group of P31c, No:159). The refined structural parameters are in agreement with the available theoretical and synchrotron radiation experimental results. Then, the infrared (IR) spectra of alpha-Si3N4 under 22 GPa were investigated with the diamond anvil cell (DAC). According to the IR absorption spectra at 296.3 K and 2 hPa (Observation range from 400 cm to 12,500 cm(-1)) we observed 23 IR active peaks. Normalized Fourier transform infrared (FTIR) absorption spectra under high pressure and room-temperature (296.3 K) show that alpha-Si3N4 undergoes a phase transition at 16.3 GPa and changes from hexagonal to cubic phase, namely, gamma-Si3N4, which is very close to the result of our theoretical calculations, i.e., the phase transition pressure is 16.3 GPa.
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语种
英语
学校署名
其他
资助项目
Postgraduate Excellent Paper Nurturing Fund of Sichuan Normal University[43]
WOS研究方向
Physics
WOS类目
Physics, Applied ; Physics, Condensed Matter ; Physics, Mathematical
WOS记录号
WOS:000462185800010
出版者
ESI学科分类
PHYSICS
来源库
Web of Science
引用统计
被引频次[WOS]:0
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/26231
专题理学院_物理系
作者单位
1.Sichuan Normal Univ, Coll Phys & Elect Engn, Chengdu 610101, Sichuan, Peoples R China
2.Southern Univ Sci & Technol, Dept Phys, Shenzhen 518055, Peoples R China
3.Univ Elect Sci & Technol, Sch Microelect & Solid State Elect, Chengdu 610054, Sichuan, Peoples R China
第一作者单位物理系
推荐引用方式
GB/T 7714
Lei, Jin-Qiao,Luo, Yan,Chen, Hong-Jie,et al. Infrared evidence for pressure-induced phase transition of alpha-Si3N4[J]. INTERNATIONAL JOURNAL OF MODERN PHYSICS B,2019,33(7).
APA
Lei, Jin-Qiao,Luo, Yan,Chen, Hong-Jie,Wang, Shan-Min,Liu, Ke,&Zhou, Xiao-Lin.(2019).Infrared evidence for pressure-induced phase transition of alpha-Si3N4.INTERNATIONAL JOURNAL OF MODERN PHYSICS B,33(7).
MLA
Lei, Jin-Qiao,et al."Infrared evidence for pressure-induced phase transition of alpha-Si3N4".INTERNATIONAL JOURNAL OF MODERN PHYSICS B 33.7(2019).
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