| 题名 | Naphthocage: A Flexible yet Extremely Strong Binder for Singly Charged Organic Cations |
| 作者 | |
| 通讯作者 | Schalley, Christoph A.; Jiang, Wei |
| 发表日期 | 2019-03-13
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| DOI | |
| 发表期刊 | |
| ISSN | 0002-7863
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| 卷号 | 141期号:10页码:4468-4473 |
| 摘要 | We report a quite flexible naphthol-based cage (so-called "naphthocage") which adopts a self-inclusion conformation in its free state and is able to bind singly charged organic cations extremely strongly (K-a > 10(7) M-1). Ion-selective electrodes prepared with this naphthocage show a super-Nernstian response to acetylcholine. In addition, the highly stable complex (10(10) M-1) between ferrocenium and the naphthocage can be switched electrochemically, which lays a basis for its application in stimuli-responsive materials. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
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| 重要成果 | NI期刊
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| 学校署名 | 通讯
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| 资助项目 | Deutsche Forschungsgemeinschaft[CRC 765]
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| WOS研究方向 | Chemistry
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| WOS类目 | Chemistry, Multidisciplinary
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| WOS记录号 | WOS:000461537700043
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| 出版者 | |
| EI入藏号 | 20191106638012
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| EI主题词 | Positive ions
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| EI分类号 | Chemical Plants and Equipment:802.1
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| 来源库 | Web of Science
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| 引用统计 |
被引频次[WOS]：50
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| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/26257 |
| 专题 | 理学院_化学系 深圳格拉布斯研究院 |
| 作者单位 | 1.Free Univ Berlin, Inst Chem & Biochem, Takustr 3, D-14195 Berlin, Germany 2.Southern Univ Sci & Technol, Dept Chem, Xueyuan Blvd 1088, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Xueyuan Blvd 1088, Shenzhen 518055, Peoples R China 4.Free Univ Berlin, Inst Chem & Biochem, Fabeckstr 34-36, D-14195 Berlin, Germany |
| 第一作者单位 | 化学系; 深圳格拉布斯研究院 |
| 通讯作者单位 | 化学系; 深圳格拉布斯研究院 |
| 推荐引用方式 GB/T 7714 |
Jia, Fei,Hupatz, Henrik,Yang, Liu-Pan,et al. Naphthocage: A Flexible yet Extremely Strong Binder for Singly Charged Organic Cations[J]. Journal of the American Chemical Society,2019,141(10):4468-4473.
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| APA |
Jia, Fei.,Hupatz, Henrik.,Yang, Liu-Pan.,Schroder, Hendrik, V.,Li, Dong-Hao.,...&Jiang, Wei.(2019).Naphthocage: A Flexible yet Extremely Strong Binder for Singly Charged Organic Cations.Journal of the American Chemical Society,141(10),4468-4473.
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| MLA |
Jia, Fei,et al."Naphthocage: A Flexible yet Extremely Strong Binder for Singly Charged Organic Cations".Journal of the American Chemical Society 141.10(2019):4468-4473.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| Jia-2019-Naphthocage（2839KB） | -- | -- | 限制开放 | -- | ||
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