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题名

p-Type Near-Infrared Transparent Delafossite Thin Films with Ultrahigh Conductivity

作者
通讯作者Zheng, Jinxing; Wei, Renhuai; Zhu, Xuebin
发表日期
2022
DOI
发表期刊
ISSN
2195-1071
卷号10
摘要
Design and implementation of efficient p-type transparent conducting (TC) oxides with excellent performance are the global material challenge. The strategy of "chemical modulation of the valence band" triggers the enthusiasm for p-type TC delafossite CuMO2. However, the low conductivity of previous CuMO2 films obstructs the development of delafossite-based electronics. Herein, a new p-type 4d transition metal Rh-based CuRhO2 film with large-size is first designed and fabricated by a facile solution method. Room-temperature conductivity as high as 735 S cm(-1) is achieved by substituting 10%Mg in Rh sites. Additionally, the acceptor-doped CuRhO2 films exhibit high near-infrared transmittance of 85-60% with low room-temperature sheet resistance of 4.28-0.18 k omega sq(-1). Furthermore, the electronic structure, electrical transport mechanism, and intra-band excitation feature for the CuRhO2 film are unveiled. The theoretical and experimental results make a great advance in p-type TC films and will pave a promising blueprint for future multifunctional opto-electronic devices.
关键词
相关链接[来源记录]
收录类别
SCI ; EI
语种
英语
学校署名
其他
资助项目
National Natural Science Foundation of China[11604337,11904154,11804126] ; Key Lab of Photovoltaic and Energy Conservation Materials, Chinese Academy of Sciences[PECL2019KF011]
WOS研究方向
Materials Science ; Optics
WOS类目
Materials Science, Multidisciplinary ; Optics
WOS记录号
WOS:000737076100001
出版者
EI入藏号
20220111427843
EI主题词
Electronic structure ; Infrared devices ; Optoelectronic devices ; Rhodium compounds ; Thin films ; Transition metals
EI分类号
Metallurgy and Metallography:531 ; Optical Devices and Systems:741.3
来源库
Web of Science
引用统计
被引频次[WOS]:5
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/264230
专题理学院_物理系
作者单位
1.Chinese Acad Sci, HFIPS, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China
2.Univ Sci & Technol China, Hefei 230026, Peoples R China
3.Southern Univ Sci & Technol, Dept Phys, Shenzhen 518055, Peoples R China
4.Chinese Acad Sci, HFIPS, Inst Plasma Phys, Hefei 230031, Peoples R China
5.Jiangsu Univ Sci & Technol, Sch Sci, Zhenjiang 212003, Jiangsu, Peoples R China
6.Chinese Acad Sci, HFIPS, High Magnet Field Lab, Hefei 230031, Peoples R China
7.Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Peoples R China
推荐引用方式
GB/T 7714
Li, Chenhui,Gong, Penglai,Zheng, Jinxing,et al. p-Type Near-Infrared Transparent Delafossite Thin Films with Ultrahigh Conductivity[J]. Advanced Optical Materials,2022,10.
APA
Li, Chenhui.,Gong, Penglai.,Zheng, Jinxing.,Zhao, Minglin.,Wei, Renhuai.,...&Sun, Yuping.(2022).p-Type Near-Infrared Transparent Delafossite Thin Films with Ultrahigh Conductivity.Advanced Optical Materials,10.
MLA
Li, Chenhui,et al."p-Type Near-Infrared Transparent Delafossite Thin Films with Ultrahigh Conductivity".Advanced Optical Materials 10(2022).
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